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Pis'ma v Zhurnal Èksperimental'noi i Teoreticheskoi Fiziki, 2018, Volume 107, Issue 8, Pages 519–524
DOI: https://doi.org/10.7868/S0370274X18080106
(Mi jetpl5554)
 

This article is cited in 1 scientific paper (total in 1 paper)

CONDENSED MATTER

Is Pauling's hypothesis violated in the hexagonal modification of ice?

M. I. Ryzhkina, I. A. Ryzhkinab

a Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, Moscow region, Russia
b Inenergy Group of Companies, Moscow, Russia
Full-text PDF (916 kB) Citations (1)
References:
Abstract: The effect of long-range dipole interaction on the fulfilment of Pauling’s hypothesis concerning the degeneracy of proton configurations satisfying the ice rules is studied for the case of hexagonal ice. It is shown that the ice rules imply a significant reduction of the contributions to the ground state energy from the next-nearest neighbors. The ground state energy of proton subsystem as a function of quasimomentum ceases to change if more than a hundred primitive unit cells in each direction are taken into account. The final amplitude of the energy changes are about 70 K. The analysis reveals the proton ordering in hexagonal ice with the simple unit cell of the oxygen sublattice is impossible. However, that does not exclude proton ordering with a more complex cell caused by distortion of the hexagonal oxygen lattice.
Funding agency Grant number
Russian Foundation for Basic Research 17-02-00512_а
Received: 17.01.2018
Revised: 16.03.2018
English version:
Journal of Experimental and Theoretical Physics Letters, 2018, Volume 107, Issue 8, Pages 500–505
DOI: https://doi.org/10.1134/S0021364018080143
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: M. I. Ryzhkin, I. A. Ryzhkin, “Is Pauling's hypothesis violated in the hexagonal modification of ice?”, Pis'ma v Zh. Èksper. Teoret. Fiz., 107:8 (2018), 519–524; JETP Letters, 107:8 (2018), 500–505
Citation in format AMSBIB
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  • This publication is cited in the following 1 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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