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Pis'ma v Zhurnal Èksperimental'noi i Teoreticheskoi Fiziki, 2017, Volume 105, Issue 2, Pages 77–86
DOI: https://doi.org/10.7868/S0370274X17020059 (Mi jetpl5167) 		 
This article is cited in 4 scientific papers (total in 4 papers)

CONDENSED MATTER

Bipolar and unipolar electrofluorescence in a molecular diode

E. G. Petrov, V. A. Leonov, Ye. V. Shevchenko

Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine
Full-text PDF (407 kB) Citations (4)
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DOI: https://doi.org/10.7868/S0370274X17020059
Abstract: It is shown that unipolar electrofluorescence different from that caused by an nonidentical shift of levels of molecular orbitals involved in electron transport can be observed in a molecular diode, where the coupling of the chloroform group of a molecule with one of the electrodes is much stronger than its coupling with the other electrode. The critical potential differences are found and conditions under which bipolarity and unipolarity are observed are determined. The performed estimates of the radiation power indicate that electrofluorescence is much more efficient in 1M2 systems exhibiting unipolarity irrespective of the Stark shift of levels. In such systems, the phenomenon of electrochromism should be expected and the probability of manifestation of electrophosphorescence in them is large.
Funding agency Grant number
National Academy of Sciences of Ukraine 0116U002067
Received: 18.10.2016
Revised: 24.12.2016
English version:
Journal of Experimental and Theoretical Physics Letters, 2017, Volume 105, Issue 2, Pages 89–97
DOI: https://doi.org/10.1134/S0021364017020126
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: E. G. Petrov, V. A. Leonov, Ye. V. Shevchenko, “Bipolar and unipolar electrofluorescence in a molecular diode”, Pis'ma v Zh. Èksper. Teoret. Fiz., 105:2 (2017), 77–86; JETP Letters, 105:2 (2017), 89–97
Citation in format AMSBIB
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    • This publication is cited in the following 4 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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