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Pis'ma v Zhurnal Èksperimental'noi i Teoreticheskoi Fiziki, 2015, Volume 102, Issue 3, Pages 179–185
DOI: https://doi.org/10.7868/S0370274X15150059 (Mi jetpl4696) 		 
This article is cited in 13 scientific papers (total in 13 papers)

CONDENSED MATTER

V$_8$C$_{7-\delta}$ superstructure in nonstoichiometric vanadium carbide powders

A. I. Guseva, A. S. Kurlova, I. A. Bobrikovb, A. M. Balagurovb

a Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620990, Russia
b Joint Institute of Nuclear Research, Dubna, Moscow region, 141980, Russia
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DOI: https://doi.org/10.7868/S0370274X15150059
Abstract: Neutron and X-ray diffraction methods have been applied jointly to study the crystal structure of the ordered phase of V$_8$C$_{7-\delta}$ in macro- and nanocrystalline vanadium carbide powders. The deviation of the composition of the ordered V$_8$C$_{7-\delta}$ phase from the stoichiometric composition V$_8$C$_7$ has been established. The magnitudes and directions of the displacements of C and V atoms have been determined. It has been shown that vanadium atoms are displaced towards a vacancy, increasing the electron density of the vacancy position of the carbon sublattice.
Received: 10.06.2015
English version:
Journal of Experimental and Theoretical Physics Letters, 2015, Volume 102, Issue 3, Pages 154–160
DOI: https://doi.org/10.1134/S0021364015150035
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: A. I. Gusev, A. S. Kurlov, I. A. Bobrikov, A. M. Balagurov, “V$_8$C$_{7-\delta}$ superstructure in nonstoichiometric vanadium carbide powders”, Pis'ma v Zh. Èksper. Teoret. Fiz., 102:3 (2015), 179–185; JETP Letters, 102:3 (2015), 154–160
Citation in format AMSBIB
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    • This publication is cited in the following 13 articles:
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