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This article is cited in 7 scientific papers (total in 7 papers)
CONDENSED MATTER
Solution-crystal-solution oscillatory phase transitions in the KCl-NaCl-H$_2$O system
V. B. Fedoseevab, M. V. Maksimovb a Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhni Novgorod, 603950, Russia
b Nizhni Novgorod State University, pr. Gagarina 23, Nizhni Novgorod, 603950, Russia
Abstract:
Long-term oscillations of a solution-crystal phase transition in the disperse KCl-NaCl-H$_2$O system have been detected. Under steady-state conditions, multiple evaporation of droplets has been observed before the formation of a crystal with subsequent condensation, which completely recovers the dimension of a droplet. An interpretation of the observed phenomenon has been proposed on the basis of the Kelvin and Ostwald–Freundlich size effects, Raoult's law, and features of the phase diagram of the KCl-NaCl system.
Received: 12.01.2015 Revised: 23.01.2015
Citation:
V. B. Fedoseev, M. V. Maksimov, “Solution-crystal-solution oscillatory phase transitions in the KCl-NaCl-H$_2$O system”, Pis'ma v Zh. Èksper. Teoret. Fiz., 101:6 (2015), 424–427; JETP Letters, 101:6 (2015), 390–393
Linking options:
https://www.mathnet.ru/eng/jetpl4582 https://www.mathnet.ru/eng/jetpl/v101/i6/p424
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Abstract page: | 171 | Full-text PDF : | 44 | References: | 40 | First page: | 4 |
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