Abstract:
An anisotropy of the propagation velocities of longitudinal and transverse ultrasonic waves, as well as of the microhardness, is observed for disordered graphite-like samples obtained from C60 fullerite by heating to different temperatures between 1000 and 1300∘C under a pressure of 7.5 GPa. The anisotropy of the elastic properties and the microhardness is attributed to the additional pressure component that occurs in the quasi-hydrostatic experimental conditions. The elastic characteristics of the samples are determined with allowance for the uniaxial orientational anisotropy. A model description relating the observed properties of superhard sp2 carbon to its possible structural features and to the mechanism of its formation is proposed.
Citation:
A. G. Glazov, V. V. Makhamad'yarov, V. V. Brazhkin, A. G. Lyapin, E. L. Gromnitskaya, O. V. Stal'gorova, S. V. Popova, “Anisotropy of the elastic properties and the microhardness of disordered superhard carbon obtained from C60 fullerite under high pressures”, Pis'ma v Zh. Èksper. Teoret. Fiz., 73:10 (2001), 621–625; JETP Letters, 73:10 (2001), 552–556