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Pis'ma v Zhurnal Èksperimental'noi i Teoreticheskoi Fiziki, 2001, Volume 73, Issue 1, Pages 41–44
(Mi jetpl4287)
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This article is cited in 12 scientific papers (total in 12 papers)
CONDENSED MATTER
Relativistic effects in PtF$_6$ and isoelectronic octahedral groups: Magnetic susceptibility, $^{19}$F NMR, and $ab$ $initio$ calculations
S. P. Gabuda, V. N. Ikorskii, S. G. Kozlova, P. S. Nikitin Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk
Abstract:
The temperature-independent paramagnetism and high $O_h$ symmetry of PtF$_6$ molecules in solids (at $77$ K) and of the octahedral molecular complexes [IrF$_6$] in KIrF$_6$ and [OsF$_6]^2$ in K$_2$OsF$_6$ are shown to be consistent with the model of strong spin-orbit coupling of $5d^4$ electrons.
Received: 01.12.2000
Citation:
S. P. Gabuda, V. N. Ikorskii, S. G. Kozlova, P. S. Nikitin, “Relativistic effects in PtF$_6$ and isoelectronic octahedral groups: Magnetic susceptibility, $^{19}$F NMR, and $ab$ $initio$ calculations”, Pis'ma v Zh. Èksper. Teoret. Fiz., 73:1 (2001), 41–44; JETP Letters, 73:1 (2001), 35–38
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https://www.mathnet.ru/eng/jetpl4287 https://www.mathnet.ru/eng/jetpl/v73/i1/p41
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Abstract page: | 141 | Full-text PDF : | 61 | References: | 1 |
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