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This article is cited in 3 scientific papers (total in 3 papers)
MISCELLANEOUS
Separation and gelation in associated systems with thermoreversible chemical bonds
R. E. Ryltsev, L. D. Son, K. Yu. Shunyaev Institute of Metallurgy, Ural Division of the Russian Academy of Sciences
Abstract:
Possible types of separation curves for a binary solution of chemically interacting molecules in a neutral solvent have been analyzed within the statistical model. It has been shown that the variation of the model parameters characterizing the energy and entropy of chemical bonds makes it possible to describe most of the possible types of solubility curves within the unified formalism. It has been demonstrated that the sol-gel transition for the case where the reactivity of molecules depends on the number of bonds can occur as a first-order phase transition; in the opposite case, gelation is a purely geometrical percolation transition.
Received: 30.08.2013 Revised: 07.10.2013
Citation:
R. E. Ryltsev, L. D. Son, K. Yu. Shunyaev, “Separation and gelation in associated systems with thermoreversible chemical bonds”, Pis'ma v Zh. Èksper. Teoret. Fiz., 98:9 (2013), 642–647; JETP Letters, 98:9 (2013), 573–577
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https://www.mathnet.ru/eng/jetpl3568 https://www.mathnet.ru/eng/jetpl/v98/i9/p642
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Abstract page: | 202 | Full-text PDF : | 66 | References: | 38 | First page: | 7 |
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