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This article is cited in 13 scientific papers (total in 13 papers)
CONDENSED MATTER
High-pressure polymorphism of $\mathrm{As}_2\mathrm{S}_3$ and new $\mathrm{As}\mathrm{S}_2$
modification with layered structure
N. B. Bolotinaa, V. V. Brazhkinb, T. I. Dyuzhevab, Y. Katayamac, L. F. Kulikovab, L. V. Lityaginab, N. A. Nikolaevb a Institute of Cristallography RAS, Moscow
b Institute for High Pressure Physics, Russian Academy of Sciences
c Japan Atomic Energy Agency
Abstract:
At normal pressure, the $\mathrm{As}_2\mathrm{S}_3$ compound is the most stable equilibrium modification with
unique layered structure. The possibility of high-pressure polymorphism of this substance
remains questionable. Our research showed that the $\mathrm{As}_2\mathrm{S}_3$ substance was metastable under pressures $P> 6$ GPa decomposing into two high-pressure phases: $\mathrm{As}_2\mathrm{S}_3\to\mathrm{AsS}_2+\mathrm{AsS}$.
New $\mathrm{As}\mathrm{S}_2$ phase can be conserved in the single crystalline form in metastable state at room pressure up to its melting temperature ($470$ K).
This modification has the layered structure with $\mathrm{P12}_11$
monoclinic symmetry group; the unit-cell values are
$a = 7.916(2)$ Å, $b = 9.937(2)$ Å,
$c = 7.118(1)$ Å, $\beta = 106.41^\circ$
($Z=8$, density $3.44$ g/cm$^3$). Along with the recently studied AsS
high-pressure modification, the new $\mathrm{As}\mathrm{S}_2$ phase suggests that high pressure polymorphism is a very powerful tool to create new layered-structure phases with “wrong” stoichiometry.
Received: 11.09.2013
Citation:
N. B. Bolotina, V. V. Brazhkin, T. I. Dyuzheva, Y. Katayama, L. F. Kulikova, L. V. Lityagina, N. A. Nikolaev, “High-pressure polymorphism of $\mathrm{As}_2\mathrm{S}_3$ and new $\mathrm{As}\mathrm{S}_2$
modification with layered structure”, Pis'ma v Zh. Èksper. Teoret. Fiz., 98:9 (2013), 608–612; JETP Letters, 98:9 (2013), 539–543
Linking options:
https://www.mathnet.ru/eng/jetpl3562 https://www.mathnet.ru/eng/jetpl/v98/i9/p608
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Abstract page: | 179 | Full-text PDF : | 59 | References: | 33 | First page: | 1 |
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