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Pis'ma v Zhurnal Èksperimental'noi i Teoreticheskoi Fiziki, 2002, Volume 76, Issue 3, Pages 199–203
(Mi jetpl2885)
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This article is cited in 8 scientific papers (total in 8 papers)
CONDENSED MATTER
Photoinduced transition of [Fe(CN)$_5$NO] nitroprusside anions to metastable states and electron localization in the (BEDT-TTF)$_4$K[Fe(CN)$_5$NO]$_2$ molecular metal
S. V. Kapel'nitskiiab, È. B. Yagubskiia, L. A. Kushcha, I. Yu. Shevyakovaa a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
b Russian Research Centre "Kurchatov Institute", Moscow
Abstract:
The crystals of (BEDT-TTF)$_4$K[Fe(CN)$_5$NO]$_2$, representing a quasi-two-dimensional organic metal with conducting layers of bis(ethylenedithio)tetrathiofulvalene (BEDT-TTF) and nonconducting layers containing pho-tochromic nitroprusside anions [Fe(CN)$_5$NO]$^{2-}$, were studied by the method of electron spin resonance. Illuminated by light with a wavelength of 514.5 nm, the organic metal crystals feature the formation of localized paramagnetic centers in the conducting cation layers of BEDT-TTF. The phenomenon of electron localization in the BEDT-TTF layers is related to the light-induced formation of long-lived metastable states of nitroprusside anions.
Received: 25.06.2002
Citation:
S. V. Kapel'nitskii, È. B. Yagubskii, L. A. Kushch, I. Yu. Shevyakova, “Photoinduced transition of [Fe(CN)$_5$NO] nitroprusside anions to metastable states and electron localization in the (BEDT-TTF)$_4$K[Fe(CN)$_5$NO]$_2$ molecular metal”, Pis'ma v Zh. Èksper. Teoret. Fiz., 76:3 (2002), 199–203; JETP Letters, 76:3 (2002), 165–169
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https://www.mathnet.ru/eng/jetpl2885 https://www.mathnet.ru/eng/jetpl/v76/i3/p199
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