Pis'ma v Zhurnal Èksperimental'noi i Teoreticheskoi Fiziki, 2002, Volume 76, Issue 3, Pages 199–203(Mi jetpl2885)
This article is cited in 8 scientific papers (total in 8 papers)
CONDENSED MATTER
Photoinduced transition of [Fe(CN)5NO] nitroprusside anions to metastable states and electron localization in the (BEDT-TTF)4K[Fe(CN)5NO]2 molecular metal
Abstract:
The crystals of (BEDT-TTF)4K[Fe(CN)5NO]2, representing a quasi-two-dimensional organic metal with conducting layers of bis(ethylenedithio)tetrathiofulvalene (BEDT-TTF) and nonconducting layers containing pho-tochromic nitroprusside anions [Fe(CN)5NO]2−, were studied by the method of electron spin resonance. Illuminated by light with a wavelength of 514.5 nm, the organic metal crystals feature the formation of localized paramagnetic centers in the conducting cation layers of BEDT-TTF. The phenomenon of electron localization in the BEDT-TTF layers is related to the light-induced formation of long-lived metastable states of nitroprusside anions.
Citation:
S. V. Kapel'nitskii, È. B. Yagubskii, L. A. Kushch, I. Yu. Shevyakova, “Photoinduced transition of [Fe(CN)5NO] nitroprusside anions to metastable states and electron localization in the (BEDT-TTF)4K[Fe(CN)5NO]2 molecular metal”, Pis'ma v Zh. Èksper. Teoret. Fiz., 76:3 (2002), 199–203; JETP Letters, 76:3 (2002), 165–169