Abstract:
The effect of activation on the size, specific volume, and surface area of pores in a monolithic biomorphic material obtained by carbonization of beech wood is studied. It is shown that under optimal activation mode with a steam heated to 970∘C, the total pore volume and surface, determined by adsorption curves, increased by 20 and 18 times, respectively. With the use of high-precision interferometric procedure, strain curves are obtained under uniaxial compression with a stepwise loading, and the strain rate is measured with a step of moving of 325 nm for activated and nonactivated samples. Despite an increase in porosity, the strength and maximum deformation of the samples do not decrease. The behavior of the strain rate jumps is analyzed in the micro- and nanometer range. It is shown that the maximum size of the micrometer jumps (4 μm) correlates well with the average size of the possible strain area in the samples (the average distance between the pores of small size), and the minimum dimensions of the strain jumps are close to the size of mesopores. Assessment of the strain change and its rate upon activation indicates that the effect of activation on the strain and strength characteristics is defined by nanometer defects, the most likely of which are microand mesopores.
Citation:
V. V. Shpeyzman, T. S. Orlova, A. A. Spitsyn, D. A. Ponomarev, N. I. Bogdanovich, J. Martínez-Fernández, “Effect of activation on the porous structure and the strain and strength properties of beech wood biocarbon”, Fizika Tverdogo Tela, 59:1 (2017), 110–115; Phys. Solid State, 59:1 (2017), 114–119
\Bibitem{ShpOrlSpi17}
\by V.~V.~Shpeyzman, T.~S.~Orlova, A.~A.~Spitsyn, D.~A.~Ponomarev, N.~I.~Bogdanovich, J.~Mart{\'\i}nez-Fern\'andez
\paper Effect of activation on the porous structure and the strain and strength properties of beech wood biocarbon
\jour Fizika Tverdogo Tela
\yr 2017
\vol 59
\issue 1
\pages 110--115
\mathnet{http://mi.mathnet.ru/ftt9715}
\crossref{https://doi.org/10.21883/FTT.2017.01.43959.242}
\elib{https://elibrary.ru/item.asp?id=28969438}
\transl
\jour Phys. Solid State
\yr 2017
\vol 59
\issue 1
\pages 114--119
\crossref{https://doi.org/10.1134/S1063783417010309}
Linking options:
https://www.mathnet.ru/eng/ftt9715
https://www.mathnet.ru/eng/ftt/v59/i1/p110
This publication is cited in the following 2 articles:
Ruixia Qin, Huadong Xu, Jiaxing Guo, Peng Wang, Kang Yang, “A study on the relationship between porosity and dielectric constant of wood considering the change of moisture content and frequency”, Holzforschung, 2025
Qian He, Tianyi Zhan, Haiyang Zhang, Zehui Ju, Lu Hong, Nicolas Brosse, Xiaoning Lu, H. Li, M. Ashraf, O. Corbi, P. Yang, L. Wang, I. Corbi, “Comparison of Bonding Performance Between Plywood and Laminated Veneer Lumber Induced by High Voltage Electrostatic Field.”, MATEC Web Conf., 275 (2019), 01013