Processing math: 100%
Fizika Tverdogo Tela
RUS  ENG    JOURNALS   PEOPLE   ORGANISATIONS   CONFERENCES   SEMINARS   VIDEO LIBRARY   PACKAGE AMSBIB  
General information
Latest issue
Archive

Search papers
Search references

RSS
Latest issue
Current issues
Archive issues
What is RSS



Fizika Tverdogo Tela:
Year:
Volume:
Issue:
Page:
Find






Personal entry:
Login:
Password:
Save password
Enter
Forgotten password?
Register


Fizika Tverdogo Tela, 2017, Volume 59, Issue 4, Pages 679–687
DOI: https://doi.org/10.21883/FTT.2017.04.44268.226
(Mi ftt9605)
 

This article is cited in 40 scientific papers (total in 40 papers)

Semiconductors

Structure, stability, and thermomechanical properties of Ca-substituted Pr2NiO4+δ

E. Yu. Pikalovaab, D. A. Medvedevab, A. F. Khasanovab

a Institute of High-Temperature Electrochemistry, RAS, Yekaterinburg, Russia
b Ural Federal University named after the First President of Russia B. N. Yeltsin, Ekaterinburg
Abstract: Ca-substituted layered nickelates with a general Pr2NiO4+δ composition (x = 0–0.7, Δx = 0.1) were prepared in the present work and their structural and physic-chemical properties were investigated in order to select the most optimal materials, which can be used as cathodes for solid oxide fuel cells. With an increase in Ca content in Pr2NiO4+δ the following tendencies were observed: (i) a decrease in the concentration of nonstoichiometric oxygen (δ), (ii) a decrease in the unit cell parameters and volume, (iii) stabilization of the tetragonal structure, (iv) a decrease of the thermal expansion coefficients, and (v) enchancement of thermodynamic stability and compatibility with selected oxygen- and proton-conducting electrolytes. The Pr2NiO4+δ material, having highest δ value, departs from the general “properties–composition” dependences ascertained. This indicates that oxygen non-stoichiometry has determining influence on the functional properties of layered nickelates.
Received: 30.05.2016
Revised: 30.07.2016
English version:
Physics of the Solid State, 2017, Volume 59, Issue 4, Pages 694–702
DOI: https://doi.org/10.1134/S1063783417040187
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: E. Yu. Pikalova, D. A. Medvedev, A. F. Khasanov, “Structure, stability, and thermomechanical properties of Ca-substituted Pr2NiO4+δ”, Fizika Tverdogo Tela, 59:4 (2017), 679–687; Phys. Solid State, 59:4 (2017), 694–702
Citation in format AMSBIB
\Bibitem{PikMedKha17}
\by E.~Yu.~Pikalova, D.~A.~Medvedev, A.~F.~Khasanov
\paper Structure, stability, and thermomechanical properties of Ca-substituted Pr$_{2}$NiO$_{4+\delta}$
\jour Fizika Tverdogo Tela
\yr 2017
\vol 59
\issue 4
\pages 679--687
\mathnet{http://mi.mathnet.ru/ftt9605}
\crossref{https://doi.org/10.21883/FTT.2017.04.44268.226}
\elib{https://elibrary.ru/item.asp?id=29257179}
\transl
\jour Phys. Solid State
\yr 2017
\vol 59
\issue 4
\pages 694--702
\crossref{https://doi.org/10.1134/S1063783417040187}
Linking options:
  • https://www.mathnet.ru/eng/ftt9605
  • https://www.mathnet.ru/eng/ftt/v59/i4/p679
  • This publication is cited in the following 40 articles:
    1. Jihai Cheng, Wenyi Zhang, Yuting Chen, Maole Zong, “Layered perovskite-like Pr2-Er NiO4 as an improved cathode for intermediate-temperature solid oxide fuel cells”, Journal of Alloys and Compounds, 2025, 179046  crossref
    2. Artem Tarutin, Liana Tarutina, Elena Filonova, “Tailoring the defect structure and functional properties of Pr2NiO4+δ via partial Pr-substitution with lanthanum and neodymium”, Ceramics International, 2024  crossref
    3. A.R. Gilev, K.S. Sukhanov, E.A. Kiselev, M.E. Sobol, V.A. Cherepanov, “Increasing thermodynamic stability and electrochemical performance of IT-SOFC cathodes based on Ln2MO4 (Ln = La, Pr; M = Ni, Cu)”, Ceramics International, 2024  crossref
    4. Elena Pikalova, Tatiana Zhulanova, Anastasia Ivanova, Artem Tarutin, Andrey Fetisov, Elena Filonova, “Optimized Pr1.6Ca0.4Ni1-yCuyO4+δ phases as promising electrode materials for CeO2- and BaCe(Zr)O3-based electrochemical cells”, Ceramics International, 2024  crossref
    5. Tatiana Zhulanova, Elena Filonova, Anastasiya Ivanova, Olga Russkikh, Elena Pikalova, “Control physicochemical and electrochemical properties of Pr1.6Ca0.4Ni0.6Cu0.4O4+δ as a prospective cathode material for solid oxide cells through the synthesis process”, Solid State Sciences, 156 (2024), 107671  crossref
    6. Phil Joo Chun, Won Bin Lim, Yoonseok Choi, “Ruddlesden-Popper Perovskite Materials for Solid Oxide Fuel Cell Cathode: A Review”, Ceramist, 27:3 (2024), 272  crossref
    7. M.A. Morales-Zapata, A. Larrea, M.A. Laguna-Bercero, “Lanthanide nickelates for their application on Solid Oxide Cells”, Electrochimica Acta, 444 (2023), 141970  crossref
    8. Qingjie Wang, Sandrine Ricote, Ming Chen, “Oxygen electrodes for protonic ceramic cells”, Electrochimica Acta, 446 (2023), 142101  crossref
    9. Artem P. Tarutin, Stanislav A. Baratov, Liana R. Tarutina, Gennady K. Vdovin, Dmitry A. Medvedev, “Ba-doped Pr2NiO4+δ electrodes for proton-conducting electrochemical cells. Part 2: Transport and electrochemical properties”, International Journal of Hydrogen Energy, 48:59 (2023), 22634  crossref
    10. Artem P. Tarutin, Elena A. Filonova, Sandrine Ricote, Dmitry A. Medvedev, Zongping Shao, “Chemical design of oxygen electrodes for solid oxide electrochemical cells: A guide”, Sustainable Energy Technologies and Assessments, 57 (2023), 103185  crossref
    11. M. V. Erpalov, A. P. Tarutin, N. A. Danilov, D. A. Osinkin, D. A. Medvedev, “Chemistry and electrochemistry of CeO<sub>2</sub>-based interlayers: Prolonging the lifetime of solid oxide fuel and electrolysis cells”, Russian Chem. Reviews, 92:10 (2023), RCR5097  mathnet  mathnet  crossref  scopus
    12. Artem P. Tarutin, Nikolai A. Danilov, Andrey A. Kalinin, Anna A. Murashkina, Dmitry A. Medvedev, “Ba-doped Pr2NiO4+δ electrodes for proton-conducting electrochemical cells. Part 1: Structure, mechanical, and chemical properties”, International Journal of Hydrogen Energy, 48:59 (2023), 22531  crossref
    13. Vipin Kamboj, Chinmoy Ranjan, Oxygen Reduction Reaction, 2022, 379  crossref
    14. Elena Filonova, Dmitry Medvedev, “Recent Progress in the Design, Characterisation and Application of LaAlO3- and LaGaO3-Based Solid Oxide Fuel Cell Electrolytes”, Nanomaterials, 12:12 (2022), 1991  crossref
    15. C. H. Wu, Y. J. Shi, F. Lu, X. S. Jia, J. R. Su, H. He, B. Cai, “Ruddlesden–Popper type La1.5xEuxPr0.5Ni0.9Cu0.1O4+δ as a potential cathode material for H-SOFC”, Phys. Solid State, 63:5 (2021), 775–784  mathnet  mathnet  crossref
    16. Linlin Zhang, Gang Chen, Ruixin Dai, Xiaohong Lv, Di Yang, Shujiang Geng, “A review of the chemical compatibility between oxide electrodes and electrolytes in solid oxide fuel cells”, Journal of Power Sources, 492 (2021), 229630  crossref
    17. Elena Pikalova, Vladislav Sadykov, Ekaterina Sadovskaya, Nikita Yeremeev, Alexander Kolchugin, Alexander Shmakov, Zakhar Vinokurov, Denis Mishchenko, Elena Filonova, Vladimir Belyaev, “Correlation between Structural and Transport Properties of Ca-Doped La Nickelates and Their Electrochemical Performance”, Crystals, 11:3 (2021), 297  crossref
    18. Artem P. Tarutin, Julia G. Lyagaeva, Dmitry A. Medvedev, Lei Bi, Aleksey A. Yaremchenko, “Recent advances in layered Ln2NiO4+δ nickelates: fundamentals and prospects of their applications in protonic ceramic fuel and electrolysis cells”, J. Mater. Chem. A, 9:1 (2021), 154  crossref
    19. A.R. Gilev, E.A. Kiselev, D.A. Malyshkin, K.S. Sukhanov, V.A. Cherepanov, “Hydration effect on properties of the La2-A Ni1-Fe O4+δ (A=Ca, Sr) cathode materials for H+-SOFCs”, Journal of Alloys and Compounds, 860 (2021), 158452  crossref
    20. Viktor A. Tsvinkinberg, Anna S. Tolkacheva, Elena A. Filonova, Olga I. Gyrdasova, Sergey M. Pikalov, Vladimir A. Vorotnikov, Aleksey I. Vylkov, Nikolay I. Moskalenko, Elena Yu Pikalova, “Structure, thermal expansion and electrical conductivity of La2–Gd NiO4+δ (0.0 ≤x≤ 0.6) cathode materials for SOFC applications”, Journal of Alloys and Compounds, 853 (2021), 156728  crossref
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
    Fizika Tverdogo Tela Fizika Tverdogo Tela
    Statistics & downloads:
    Abstract page:70
    Full-text PDF :29
     
      Contact us:
     Terms of Use  Registration to the website  Logotypes © Steklov Mathematical Institute RAS, 2025