Abstract:
CuV2O6 and Cu2V2O7 compounds have been produced from initial components CuO and V2O5 by solid-phase synthesis. The high-temperature heat capacity of the oxide compounds has been measured using differential scanning calorimetry. The thermodynamic properties (the enthalpy change, the entropy change, and the reduced Gibbs energy) have been calculated using experimental dependences CP=f(T). It is found that there is a correlation between the specific heat capacity and the composition of oxides of the CuO–V2O5 system.
Citation:
L. T. Denisova, N. V. Belousova, V. M. Denisov, N. A. Galiakhmetova, “High-temperature heat capacity of oxides of the CuO–V2O5 system”, Fizika Tverdogo Tela, 59:6 (2017), 1243–1246; Phys. Solid State, 59:6 (2017), 1270–1274
\Bibitem{DenBelDen17}
\by L.~T.~Denisova, N.~V.~Belousova, V.~M.~Denisov, N.~A.~Galiakhmetova
\paper High-temperature heat capacity of oxides of the CuO--V$_{2}$O$_{5}$ system
\jour Fizika Tverdogo Tela
\yr 2017
\vol 59
\issue 6
\pages 1243--1246
\mathnet{http://mi.mathnet.ru/ftt9567}
\crossref{https://doi.org/10.21883/FTT.2017.06.44500.407}
\elib{https://elibrary.ru/item.asp?id=29405135}
\transl
\jour Phys. Solid State
\yr 2017
\vol 59
\issue 6
\pages 1270--1274
\crossref{https://doi.org/10.1134/S1063783417060075}
Linking options:
https://www.mathnet.ru/eng/ftt9567
https://www.mathnet.ru/eng/ftt/v59/i6/p1243
This publication is cited in the following 8 articles:
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Mireille Ghoussoub, Paul N. Duchesne, Meikun Xia, Feysal M. Ali, Shoushou He, Navid Soheilnia, Geoffrey A. Ozin, “Kinetics and Mechanism of Turanite Reduction by Hydrogen”, J. Phys. Chem. C, 124:33 (2020), 18356
Luan Pereira Camargo, Adriana Campano Lucilha, Guilherme Augusto Barros Gomes, Vanessa Rocha Liberatti, Avacir Casanova Andrello, Paulo Rogério Catarini da Silva, Luiz Henrique Dall'Antonia, “Copper pyrovanadate electrodes prepared by combustion synthesis: evaluation of photoelectroactivity”, J Solid State Electrochem, 24:8 (2020), 1935
L. T. Denisova, Yu. F. Kargin, N. V. Belousova, N. A. Galiakhmetova, V. M. Denisov, “Synthesis and Investigation of Thermodynamic Properties of Cu5V2O10”, Russ. J. Inorg. Chem., 64:6 (2019), 725
Hui Wang, Mengjie Yang, Mingju Chao, Juan Guo, Qilong Gao, Yajie Jiao, Xinbo Tang, Erjun Liang, “Negative thermal expansion property of β-Cu2V2O7”, Solid State Ionics, 343 (2019), 115086
Mohammad K. Hossain, Paola Sotelo, Hori P. Sarker, Miguel T. Galante, Attila Kormányos, Claudia Longo, Robin T. Macaluso, Mohammad N. Huda, Csaba Janáky, Krishnan Rajeshwar, “Rapid One-Pot Synthesis and Photoelectrochemical Properties of Copper Vanadates”, ACS Appl. Energy Mater., 2:4 (2019), 2837
L. T. Denisova, N. V. Belousova, N. A. Galiakhmetova, V. M. Denisov, E. O. Golubeva, “High-temperature heat capacity of Zn$_{2}$V$_{2}$O$_{7}$–Cu$_{2}$V$_{2}$O$_{7}$ solid solutions”, Phys. Solid State, 60:7 (2018), 1303–1307
L. T. Denisova, L. G. Chumilina, N. V. Belousova, V. M. Denisov, N. A. Galiakhmetova, “High-temperature heat capacity of CdO–V$_{2}$O$_{5}$ oxides”, Phys. Solid State, 59:12 (2017), 2519–2523