Abstract:
Chemical carbonization of polyvinylidene fluoride is necessary for the synthesis on its basis of quasi-one-dimensional carbon structures having a prospect of use in microelectronics. To determine the details of the carbonization process, the concentrations of $^{19}$F and $^{1}$H nuclei were measured and the changes in the concentration of CF$_{2}$, CH$_{2}$, and OH groups in partially dehydrofluorinated polyvinylidene fluoride samples were studied using nuclear magnetic resonance and infrared spectroscopy. The efficiency of substitution of fluorine and hydrogen atoms by OH groups in the process of dehydrofluorination of polymer chains is estimated.
Citation:
V. E. Zhivulin, V. M. Chernov, A. A. Osipov, M. V. Shtenberg, S. E. Evsyukov, L. A. Pesin, “Analysis of the change in the concentration of fluorine and hydrogen as a result of chemical dehydrofluorination of polyvinylidene fluoride”, Fizika Tverdogo Tela, 59:7 (2017), 1387–1392; Phys. Solid State, 59:7 (2017), 1414–1419
\Bibitem{ZhiCheOsi17}
\by V.~E.~Zhivulin, V.~M.~Chernov, A.~A.~Osipov, M.~V.~Shtenberg, S.~E.~Evsyukov, L.~A.~Pesin
\paper Analysis of the change in the concentration of fluorine and hydrogen as a result of chemical dehydrofluorination of polyvinylidene fluoride
\jour Fizika Tverdogo Tela
\yr 2017
\vol 59
\issue 7
\pages 1387--1392
\mathnet{http://mi.mathnet.ru/ftt9531}
\crossref{https://doi.org/10.21883/FTT.2017.07.44604.148}
\elib{https://elibrary.ru/item.asp?id=29772442}
\transl
\jour Phys. Solid State
\yr 2017
\vol 59
\issue 7
\pages 1414--1419
\crossref{https://doi.org/10.1134/S1063783417070332}
Linking options:
https://www.mathnet.ru/eng/ftt9531
https://www.mathnet.ru/eng/ftt/v59/i7/p1387
This publication is cited in the following 6 articles:
Ilya A. Zavidovskiy, Oleg A. Streletskiy, Islam F. Nuriahmetov, Olesya Yu. Nishchak, Natalya F. Savchenko, Andrey A. Tatarintsev, Alexander V. Pavlikov, “Highly Selective Polyene-Polyyne Resistive Gas Sensors: Response Tuning by Low-Energy Ion Irradiation”, J. Compos. Sci., 7:4 (2023), 156
V. E. Zhivulin, S. E. Evsyukov, D. A. Chalov, V. M. Morilova, V. P. Andreychuk, R. Kh. Khairanov, I. G. Margamov, L. A. Pesin, “Evolution of the Molecular Structure of Partially Dehydrofluorinated Poly(Vinylidene Fluoride) Films upon Storage in Air”, J. Surf. Investig., 16:5 (2022), 673
V. E. Zhivulin, N. A. Zlobina, S. E. Evsyukov, L. A. Pesin, “Changes in the Shape of the CH Absorption Band in the IR Spectra of the Chemicaly Dehydrofluorinated Poly(Vinylidene Fluoride) Film During Aging”, J. Synch. Investig., 15:1 (2021), 12
L. A. Pesin, “Radiation-induced Carbonization of Polyvinylidene Fluoride: Part I (Review)”, J. Surf. Investig., 15:6 (2021), 1296
V.E. Zhivulin, L.A. Pesin, E.A. Belenkov, V.A. Greshnyakov, N. Zlobina, M. Brzhezinskaya, “Ageing of chemically modified poly(vinylidene fluoride) film: Evolution of triple carbon-carbon bonds infrared absorption”, Polymer Degradation and Stability, 172 (2020), 109059
V. E. Zhivulin, R. Kh. Khairanov, N. A. Zlobina, L. A. Pesin, “Modification of the IR Spectra Shape in the 2000–2300 cm–1 Absorption Band upon the Aging of a Chemically Dehydrofluorinated Poly(vinylidene fluoride) Film”, J. Synch. Investig., 14:6 (2020), 1144