Abstract:
New relationships have been obtained in an integral form for binary systems in the case when one of the phases is dispersed (to nanometer sizes) inside another phase (matrix) in the framework of the thermodynamics of phase equilibrium, including surface phenomena. These relationships are used to construct a size-dependent phase diagram in the binary Mo–Ru system containing solid nanoparticles with bcc and hcp structures and a liquid phase in equilibrium conditions. The calculations are performed with the successive inclusion of the size dependences of the characteristics of pure components and the parameter of the interparticle interaction in the phases. The calculated results agree with the experimental data in the microscopic case.
Citation:
M. A. Shebzukhova, A. A. Shebzukhov, “Influence of the nanodimensional effects on the composition of coexisting phases in a binary system with curved boundaries”, Fizika Tverdogo Tela, 59:7 (2017), 1368–1378; Phys. Solid State, 59:7 (2017), 1395–1405
\Bibitem{SheShe17}
\by M.~A.~Shebzukhova, A.~A.~Shebzukhov
\paper Influence of the nanodimensional effects on the composition of coexisting phases in a binary system with curved boundaries
\jour Fizika Tverdogo Tela
\yr 2017
\vol 59
\issue 7
\pages 1368--1378
\mathnet{http://mi.mathnet.ru/ftt9529}
\crossref{https://doi.org/10.21883/FTT.2017.07.44602.410}
\elib{https://elibrary.ru/item.asp?id=29772440}
\transl
\jour Phys. Solid State
\yr 2017
\vol 59
\issue 7
\pages 1395--1405
\crossref{https://doi.org/10.1134/S1063783417070253}
Linking options:
https://www.mathnet.ru/eng/ftt9529
https://www.mathnet.ru/eng/ftt/v59/i7/p1368
This publication is cited in the following 7 articles:
A. A. Afashagov, M. A. Shebzukhova, K. Ch. Bzhikhatlov, A. Kh. Tsipinova, “Nanosize Dependence of the Mutual Solubility in the Solid State in the Mo–Ru Metal System”, Fizika metallov i metallovedenie, 124:10 (2023), 939
A. A. Afashagov, M. A. Shebzukhova, K. Ch. Bzhikhatlov, A. Kh. Tsipinova, “Nanosize Dependence of the Mutual Solubility in the Solid State in a Mo–Ru Metal System”, Phys. Metals Metallogr., 124:10 (2023), 995
A. A. Afashagov, M. A. Shebzukhova, A. A. Shebzukhov, “Thermodynamic Characteristics of the Interface between Condensed Phases in Binary Metal Alloys”, Phys. Solid State, 64:6 (2022), 293
M. A. Shebzukhova, A. A. Shebzukhov, K. Ch. Bzhikhatlov, V. K. Lyuyev, “Surface Tension and Parameters of Interatomic Interaction on Surfaces of Binary Solutions”, Bull. Russ. Acad. Sci. Phys., 83:6 (2019), 749
M. A. Shebzukhova, “Size Dependence of Adsorption and Interphase Tension at the Boundary between Nanoparticles and the Matrix in a Binary System”, Bull. Russ. Acad. Sci. Phys., 82:7 (2018), 797
M. A. Shebzukhova, A. A. Shebzukhov, “Phase equilibrium and surface properties of a binary system containing nanoparticles”, Phys. Solid State, 60:2 (2018), 397–403
M. A. Shebzukhova, A. A. Shebzukhov, “Phase diagram and interfacial characteristics in a binary system”, Phys. Solid State, 60:1 (2018), 183–190