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This article is cited in 2 scientific papers (total in 2 papers)
Atomic clusters
Yttrium-containing endohedral metallofullerenes: Synthesis and extraction
G. N. Churilovab, N. G. Vnukovaab, E. V. Tomashevichc, A. I. Dudnika, G. A. Glushenkoa, I. A. Dubininaab, U. E. Guliaevaab, E. I. Melnikovab a L. V. Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk
b Siberian Federal University, Krasnoyarsk
c Institute of Chemistry and Chemical Technology SB RAS, Krasnoyarsk
Abstract:
Yttrium-containing endohedral metallofullerenes are synthesized in an RF arc discharge in the helium flow with embedded Y$_{2}$O$_{3}$. It is shown that the formation of the metallofullerenes depends on the helium pressure in a chamber; however, this dependence cannot be explained using the model of formation of conventional fullerenes without a guest atom in a molecule. The results of extraction of Y@C$_{82}$ by pyridine and carbon disulfide are reported. The pressure corresponding to the maximum yttrium-containing endohedral metallofullerene content is shown to be 60 kPa; under this pressure, extraction by carbon disulfide allows obtaining 27.1 wt % of the endohedral metallofullerene, while extraction by pyridine yields its amount of 17.3 wt%.
Received: 24.10.2016 Revised: 20.01.2017
Citation:
G. N. Churilov, N. G. Vnukova, E. V. Tomashevich, A. I. Dudnik, G. A. Glushenko, I. A. Dubinina, U. E. Guliaeva, E. I. Melnikova, “Yttrium-containing endohedral metallofullerenes: Synthesis and extraction”, Fizika Tverdogo Tela, 59:8 (2017), 1638–1641; Phys. Solid State, 59:8 (2017), 1662–1665
Linking options:
https://www.mathnet.ru/eng/ftt9505 https://www.mathnet.ru/eng/ftt/v59/i8/p1638
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