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Phase transitions
Kinetics of the growth of filamentary KH$_{2}$PO$_{4}$ crystals on a seed crystal
E. K. Titaevaa, M. S. Kuritsynb, A. N. Noskovaa, V. N. Portnova a National Research Lobachevsky State University of Nizhny Novgorod
b Institute of Applied Physics, Russian Academy of Sciences, Nizhny Novgorod
Abstract:
At oversaturations exceeding the inert range end for face $\{101\}$ due to the presence of admixture Al(NO$_{3}$)$_{3}$ $\cdot$ 9H$_{2}$O, a new phase is observed during the growth of this face in the form of filamentary crystals. Some experimental dependences of the growth rate of filamentary potassium dihydrophosphate (KH$_{2}$PO$_{4}$ ) crystals on the oversaturation have been obtained at different admixture concentrations. The growth of filamentary crystals occurs by the mechanism of two-dimensional nucleation. Their formation is governed by the effect of [AlHPO$_{4}$]$^{+}$ complexes in the form of Cabrera and Vermilyea stoppers.
Received: 16.08.2016 Revised: 20.12.2016
Citation:
E. K. Titaeva, M. S. Kuritsyn, A. N. Noskova, V. N. Portnov, “Kinetics of the growth of filamentary KH$_{2}$PO$_{4}$ crystals on a seed crystal”, Fizika Tverdogo Tela, 59:8 (2017), 1594–1597; Phys. Solid State, 59:8 (2017), 1619–1622
Linking options:
https://www.mathnet.ru/eng/ftt9498 https://www.mathnet.ru/eng/ftt/v59/i8/p1594
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Abstract page: | 34 | Full-text PDF : | 14 |
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