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This article is cited in 6 scientific papers (total in 6 papers)
Ferroelectricity
AC conductivity of BiFeO$_{3}$ ceramics obtained by spark plasma sintering of nanopowder
S. A. Sadykova, D. K. Palchaevab, Zh. Kh. Murlievaac, N. M.-R. Alikhanova, M. Kh. Rabadanova, S. Kh. Gadzhimagomedova, S. N. Kallaevd a Daghestan State University, Makhachkala
b Southern Federal University, Rostov-on-Don
c Dagestan State University of National Economy
d Daghestan Institute of Physics after Amirkhanov, Makhachkala, Dagestan Republic, Russia
Abstract:
The structure and electrical properties of BiFeO$_{3}$ ceramics obtained by spark plasma sintering of a nanopowder are investigated. The nanopowder was synthesized by burning of an organic nitrate precursor. The ac conductivity was measured in a frequency range of 1 kHz–10 MHz in a temperature interval of 25–500$^\circ$C. It is established that the temperature conductivity coefficients above and below $\sim$350$^\circ$C significantly differ with both alternating and direct currents. The frequency dependence of the conductivity obeys the Jonscher power law $\sigma\sim\omega^s$, where $s<$ 1. The interpretation of this behavior is given in the framework of the model of correlated hops of charge carriers over potential barriers. It is assumed that the hopping mechanism is realized between Fe$^{2+}$ and Fe$^{3+}$ ions in ceramic grains. The role of oxygen vacancies in the conduction is also discussed.
Received: 30.01.2017 Revised: 07.03.2017
Citation:
S. A. Sadykov, D. K. Palchaev, Zh. Kh. Murlieva, N. M.-R. Alikhanov, M. Kh. Rabadanov, S. Kh. Gadzhimagomedov, S. N. Kallaev, “AC conductivity of BiFeO$_{3}$ ceramics obtained by spark plasma sintering of nanopowder”, Fizika Tverdogo Tela, 59:9 (2017), 1747–1753; Phys. Solid State, 59:9 (2017), 1771–1777
Linking options:
https://www.mathnet.ru/eng/ftt9459 https://www.mathnet.ru/eng/ftt/v59/i9/p1747
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