Abstract:
The size effects on the composition of coexisting phases, the interfacial layer between them, and the interfacial tension in a binary system composed of a matrix and the monodispersed particles of arbitrary (including nanoscale) size are described in the context of a Gibbs method for dispersed systems. Obtaining the relevant relationships has allowed plotting the size-dependent phase state diagrams for a Cr–Ti system with a point of equal concentrations with a minimum. The coefficients of size composition of the nanoparticles and the matrix, as well as those of interfacial tension under the isobaric and isothermal conditions, are calculated at different degree of dispersion. The calculated data coincide with the experimental ones.
Citation:
M. A. Shebzukhova, A. A. Shebzukhov, “Phase diagram and interfacial characteristics in a binary system”, Fizika Tverdogo Tela, 60:1 (2018), 180–186; Phys. Solid State, 60:1 (2018), 183–190
\Bibitem{SheShe18}
\by M.~A.~Shebzukhova, A.~A.~Shebzukhov
\paper Phase diagram and interfacial characteristics in a binary system
\jour Fizika Tverdogo Tela
\yr 2018
\vol 60
\issue 1
\pages 180--186
\mathnet{http://mi.mathnet.ru/ftt9346}
\crossref{https://doi.org/10.21883/FTT.2018.01.45307.099}
\elib{https://elibrary.ru/item.asp?id=32737398}
\transl
\jour Phys. Solid State
\yr 2018
\vol 60
\issue 1
\pages 183--190
\crossref{https://doi.org/10.1134/S1063783418010225}
Linking options:
https://www.mathnet.ru/eng/ftt9346
https://www.mathnet.ru/eng/ftt/v60/i1/p180
This publication is cited in the following 3 articles:
A. A. Afashagov, M. A. Shebzukhova, K. Ch. Bzhikhatlov, A. Kh. Tsipinova, “Nanosize Dependence of the Mutual Solubility in the Solid State in the Mo–Ru Metal System”, Fizika metallov i metallovedenie, 124:10 (2023), 939
A. A. Afashagov, M. A. Shebzukhova, K. Ch. Bzhikhatlov, A. Kh. Tsipinova, “Nanosize Dependence of the Mutual Solubility in the Solid State in a Mo–Ru Metal System”, Phys. Metals Metallogr., 124:10 (2023), 995
A. A. Afashagov, M. A. Shebzukhova, A. A. Shebzukhov, “Thermodynamic Characteristics of the Interface between Condensed Phases in Binary Metal Alloys”, Phys. Solid State, 64:6 (2022), 293