Abstract:
The dielectric spectra of Pb(1−z)Baz (Mg1/3Nb2/3)m (Zn1/3Nb2/3)y (Ni1/3Nb2/3)nTixO3 (x = 0.25–0.4, y = 0.1130–0.0842, m = 0.4844–0.1298, n = 0.1266–0.4726, z = 0–0.15) ceramics with substitution in both A and B crystallographic positions of the perovskite structure are studied. The system demonstrates a transition from the relaxor state to the normal ferroelectric state in both cases: when the concentration of lead titanate grows and the concentration of barium is reduced. On the basis of experimental results, the x–T and z–T phase diagrams are plotted. Despite different crystal chemical reasons of the relaxor state emergence in the investigated solid solutions, their diagrams demonstrate an evident similarity. We have revealed the disappearance of the temperature hysteresis at the transition to the relaxor state in both cases, which has allowed us to make an assumption of the existence of tricritical points on the corresponding diagrams.
Citation:
M. V. Talanov, L. A. Reznichenko, “Phase diagrams of solid solutions of relaxor ferroelectrics from the dielectric spectroscopy data”, Fizika Tverdogo Tela, 60:3 (2018), 435–438; Phys. Solid State, 60:3 (2018), 437–441
\Bibitem{TalRez18}
\by M.~V.~Talanov, L.~A.~Reznichenko
\paper Phase diagrams of solid solutions of relaxor ferroelectrics from the dielectric spectroscopy data
\jour Fizika Tverdogo Tela
\yr 2018
\vol 60
\issue 3
\pages 435--438
\mathnet{http://mi.mathnet.ru/ftt9258}
\crossref{https://doi.org/10.21883/FTT.2018.03.45540.10D}
\elib{https://elibrary.ru/item.asp?id=32739799}
\transl
\jour Phys. Solid State
\yr 2018
\vol 60
\issue 3
\pages 437--441
\crossref{https://doi.org/10.1134/S1063783418030319}
Linking options:
https://www.mathnet.ru/eng/ftt9258
https://www.mathnet.ru/eng/ftt/v60/i3/p435
This publication is cited in the following 5 articles:
M. V. Talanov, E. V. Glazunova, V. I. Kozlov, S. P. Kubrin, A. A. Bush, V. M. Talanov, K. E. Kamentsev, “Dielectric properties of bismuth-containing pyrochlores: A comparative analysis”, J. Adv. Dielect., 12:02 (2022)
M.V. Talanov, Pyrochlore Ceramics, 2022, 295
M. V. Talanov, A. A. Pavelko, L. A. Reznichenko, “Low- and high-field electromechanical responses of relaxor-based multicomponent ceramics for application in multiregime actuators”, J. Adv. Dielect., 10:01n02 (2020), 2060004
Mikhail V. Talanov, Alexei A. Bokov, Mikhail A. Marakhovsky, “Effects of crystal chemistry and local random fields on relaxor and piezoelectric behavior of lead-oxide perovskites”, Acta Materialia, 193 (2020), 40
M. V. Talanov, V. V. Ivanov, N. N. Bolshakova, S. A. Borisenko, L. A. Reznichenko, “Dielectric anomalies of the PMN-PT-based multicomponent ceramics in electric fields”, Ferroelectrics, 543:1 (2019), 101