Abstract:
It is established both experimentally and by calculations that the nuclei of CuCl phase do not form in the solid solution of CuCl in the glass at the temperature Tu⩾600∘C. At the temperature of 500∘C, nuclei do not form due to a low diffusion coefficient. In the temperature range of 500–600∘C maximums of the flow of new clusters and the critical radius are almost at the same temperature. The supersaturation is minimal in the area of maximum. The experimental dependence of the formation rate of CuCl clusters on temperature is in a good agreement with the calculated one. It is shown that the concentration of nuclei, its average radius, and the width of distribution by radii can be effectively controlled using the cooling “on the top.” The narrow distributions of CuCl clusters in the glass with the relative half-width of about 3.7% are obtained.
Citation:
V. I. Leiman, A. L. Ashkalunin, P. M. Valov, O. Yu. Derkacheva, V. M. Maksimov, “Nonisothermal nucleation in the solid solution CuCl in glass: temperature range of the formation of supercritical nuclei of CuCl phase”, Fizika Tverdogo Tela, 60:5 (2018), 984–988; Phys. Solid State, 60:5 (2018), 995–999
\Bibitem{LeiAshVal18}
\by V.~I.~Leiman, A.~L.~Ashkalunin, P.~M.~Valov, O.~Yu.~Derkacheva, V.~M.~Maksimov
\paper Nonisothermal nucleation in the solid solution CuCl in glass: temperature range of the formation of supercritical nuclei of CuCl phase
\jour Fizika Tverdogo Tela
\yr 2018
\vol 60
\issue 5
\pages 984--988
\mathnet{http://mi.mathnet.ru/ftt9210}
\crossref{https://doi.org/10.21883/FTT.2018.05.45799.241}
\elib{https://elibrary.ru/item.asp?id=32739891}
\transl
\jour Phys. Solid State
\yr 2018
\vol 60
\issue 5
\pages 995--999
\crossref{https://doi.org/10.1134/S1063783418050165}
Linking options:
https://www.mathnet.ru/eng/ftt9210
https://www.mathnet.ru/eng/ftt/v60/i5/p984
This publication is cited in the following 1 articles:
A. L. Ashkalunin, E. S. Derkacheva, V. O. Kabanov, V. I. Leiman, “Nucleation of CuCl in Glass at the Sample Heating Stage”, Glass Phys Chem, 45:6 (2019), 491