A. S. Kamzin, H. Das, N. Wakiya, A. A. Valiullin, “Magnetic core/shell nanocomposites MgFe$_{2}$O$_{4}$/SiO$_{2}$ for biomedical application: synthesis and properties”, Fizika Tverdogo Tela, 60:9 (2018), 1707–1716; Phys. Solid State, 60:9 (2018), 1752

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Fizika Tverdogo Tela, 2018, Volume 60, Issue 9, Pages 1707–1716
DOI: https://doi.org/10.21883/FTT.2018.09.46388.019 (Mi ftt9074)

This article is cited in 19 scientific papers (total in 19 papers)

Magnetism

Magnetic core/shell nanocomposites MgFe

_{2}

$_{2}$ O

_{4}

$_{4}$ /SiO

_{2}

$_{2}$ for biomedical application: synthesis and properties

A. S. Kamzin^a, H. Das^bc, N. Wakiya^de, A. A. Valiullin^f

^a Ioffe Institute, St. Petersburg
^b Graduate School of Science and Technology, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, Japan
^c Materials Science Division, Atomic Energy Centre, Dhaka 1000, Bangladesh
^d Department of Electronics and Materials Science, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, Japan
^e Research Institute of Electronics, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, Japan
^f Kazan (Volga Region) Federal University

Full-text PDF (1169 kB) Citations (19)

DOI: https://doi.org/10.21883/FTT.2018.09.46388.019

Abstract: Magnetic core/shell (CS) nanocomposites (MNCs) are synthesized using a simple method, in which a magnesium ferrite nanoparticle (MgFe

_{2}

$_{2}$ O

_{4}

$_{4}$ ) is a core, and an amorphous silicon dioxide (silica SiO

_{2}

$_2$ ) layer is a shell. The composition, morphology, and structure of synthesized particles are studied using X-ray diffraction, field emission electron microscopy, transmission electron microscopy (TEM), energy-dispersive spectroscopy (EDS), scattering electrophoretic photometer, thermogravimetric analysis (TGA), and Mössbauer spectroscopy. It is found that the MgFe

_{2}

$_{2}$ O

_{4}

$_{4}$ /SiO

_{2}

$_2$ MNC has the core/shell structure formed by the Fe–O–Si chemical bond. After coating with silica, the MgFe

_{2}

$_{2}$ O

_{4}

$_{4}$ /SiO

_{2}

$_2$ MNC saturation magnetization significantly decreases in comparison with MgFe

_{2}

$_{2}$ O

_{4}

$_{4}$ particles without a SiO

_{2}

$_2$ shell. Spherical particles agglomerated from MgFe

_{2}

$_2$ O

_{4}

$_4$ nanocrystallites

\sim

$\sim$ 9.6 and

\sim

$\sim$ 11.5 nm in size function as cores coated with SiO

_{2}

$_2$ shells

\sim

$\sim$ 30 and

\sim

$\sim$ 50 nm thick, respectively. The total size of obtained CS MNCs is

\sim

$\sim$ 200 and 300 nm, respectively. Synthesized CS MgFe

_{2}

$_2$ O

_{4}

$_4$ /SiO

_{2}

$_2$ MNCs are very promising for biomedical applications, due to the biological compatibility of silicon dioxide, its sizes, and the fact that the Curie temperature is in the region required for hyperthermal therapy, 320 K.

Received: 23.01.2018
Revised: 15.03.2018

English version:
Physics of the Solid State, 2018, Volume 60, Issue 9, Pages 1752–1761
DOI: https://doi.org/10.1134/S1063783418090147

Bibliographic databases:

Document Type: Article

Language: Russian

Citation: A. S. Kamzin, H. Das, N. Wakiya, A. A. Valiullin, “Magnetic core/shell nanocomposites MgFe

_{2}

$_{2}$ O

_{4}

$_{4}$ /SiO

_{2}

$_{2}$ for biomedical application: synthesis and properties”, Fizika Tverdogo Tela, 60:9 (2018), 1707–1716; Phys. Solid State, 60:9 (2018), 1752–1761

Citation in format AMSBIB

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\by A.~S.~Kamzin, H.~Das, N.~Wakiya, A.~A.~Valiullin

\paper Magnetic core/shell nanocomposites MgFe$_{2}$O$_{4}$/SiO$_{2}$ for biomedical application: synthesis and properties

\jour Fizika Tverdogo Tela

\yr 2018

\vol 60

\issue 9

\pages 1707--1716

\mathnet{http://mi.mathnet.ru/ftt9074}

\crossref{https://doi.org/10.21883/FTT.2018.09.46388.019}

\elib{https://elibrary.ru/item.asp?id=36903688}

\transl

\jour Phys. Solid State

\yr 2018

\vol 60

\issue 9

\pages 1752--1761

\crossref{https://doi.org/10.1134/S1063783418090147}

Linking options:

https://www.mathnet.ru/eng/ftt9074

https://www.mathnet.ru/eng/ftt/v60/i9/p1707

This publication is cited in the following 19 articles:

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Saeid Taghavi Fardood, Sara Ganjkhanlu, Farzaneh Moradnia, Ali Ramazani, “Green synthesis, characterization, and photocatalytic activity of superparamagnetic MgFe2O4@ZnAl2O4 nanocomposites”, Sci Rep, 14:1 (2024)
Yu. V. Knyazev, D. A. Balaev, S. A. Skorobogatov, D. A. Velikanov, O. A. Bayukov, S. V. Stolyar, V. P. Ladygina, A. A. Krasikov, R. S. Iskhakov, “Superparamagnetic Relaxation in Ensembles of Ultrasmall Ferrihydrite Nanoparticles”, Phys. Metals Metallogr., 125:4 (2024), 377
Yu. V. Knyazev, D. A. Balaev, S. A. Skorobogatov, D. A. Velikanov, O. A. Bayukov, S. V. Stolyar, V. P. Ladygina, A. A. Krasikov, R. S. Iskhakov, “Superparamagnetic Relaxation in Ensembles of Ultrasmall Ferrihydrite Nanoparticles”, Fizika metallov i metallovedenie, 125:4 (2024), 420
E. V. Tomina, B. V. Sladkopevtsev, Nguyen Anh Tien, Vo Quang Mai, “Nanocrystalline Ferrites with Spinel Structure for Various Functional Applications”, Inorg Mater, 59:13 (2023), 1363
Subiya K. Kazi, Shaukatali N. Inamdar, Dhanraj P. Kamble, Kishan S. Lohar, Appasaheb W. Suryawanshi, Radhakrishnan M. Tigote, “Structural studies of silica‐supported spinel magnesium ferrite nanorods for photocatalytic degradation of methyl orange”, J Chinese Chemical Soc, 69:7 (2022), 1032
T.A. Taha, Moataz G. Fayed, Saad G. Mohamed, “Enhanced electrochemical performance of MgFe2O4/SrTiO3 and MgFe2O4/SiO2 nanocomposite structures”, Journal of Alloys and Compounds, 925 (2022), 166660
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Min Yang, Guangshe Li, Huixia Li, Junfang Ding, Yan Wang, Liping Li, “Growth kinetic control over MgFe2O4 to tune Fe occupancy and metal–support interactions for optimum catalytic performance”, CrystEngComm, 23:13 (2021), 2538
Heba G. El‐Attar, Mohamed A. Salem, Eman A. Bakr, “Facile synthesis of recoverable superparamagnetic AgFeO2@Polypyrrole/SiO2 nanocomposite as an excellent catalyst for reduction and oxidation of different dyes in wastewater”, Applied Organom Chemis, 35:10 (2021)
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A. S. Kamzin, I. M. Obaidat, A. A. Valiullin, V. G. Semenov, I. A. Al-Omari, “The composition and magnetic structure of Fe$_{3}$O$_{4}$/$\gamma$-Fe$_{2}$O$_{3}$ core–shell nanocomposites at 300 and 80 K: Mössbauer study (Part I)”, Phys. Solid State, 62:10 (2020), 1933–1943
A. S. Kamzin, I. M. Obaidat, A. A. Valiullin, V. G. Semenov, I. A. Al-Omari, “The composition and magnetic structure of Fe$_{3}$O$_{4}$/$\gamma$-Fe$_{2}$O$_{3}$ core-shell nanocomposites under external magnetic field: Mössbauer study (Part II)”, Phys. Solid State, 62:11 (2020), 2167–2172
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Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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