Abstract:
Some specific features of the crystal and magnetic structures of granular powder spinel-like ferrites Mn$_{0.160}$Mg$_{0.404}$Zn$_{0.448}$Fe$_{2}$O$_{4}$, Mn$_{0.676}$Zn$_{0.227}$Fe$_{0.09}$Fe$_{2}$O$_{4}$, Mn$_{0.5792}$Zn$_{0.2597}$Fe$_{0.1612}$Fe$_{2}$O$_{4}$, and Ni$_{0.32}$Zn$_{0.68}$Fe$_{2}$O$_{4}$ have been studied by neutron diffraction. It has been established that the crystal structure of all the studied compounds has a cubic symmetry with space group $Fd\bar3m$. Ferrimagnetic ordering is observed in all the studied structures. Based on the experimental data, the unit cell parameters and interatomic bond lengths of the studied compounds are determined alongside with the distribution of cations between octahedral and tetrahedral crystallographic positions in their cubic crystal structure. Corresponding average magnetic moments are calculated for different positions in their cubic structure. Some structural mechanisms of the formation of magnetic properties depending on the level of doping and the size of powder grains are discussed.
Citation:
B. K. Argymbek, S. E. Kichanov, D. P. Kozlenko, E. V. Lukin, A. T. Morchenko, S. H. Jabarov, B. N. Savenko, “Crystal and magnetic structures of granular powder spinel Mn–Zn- and Ni–Zn ferrites”, Fizika Tverdogo Tela, 60:9 (2018), 1683–1688; Phys. Solid State, 60:9 (2018), 1727–1732
\Bibitem{ArgKicKoz18}
\by B.~K.~Argymbek, S.~E.~Kichanov, D.~P.~Kozlenko, E.~V.~Lukin, A.~T.~Morchenko, S.~H.~Jabarov, B.~N.~Savenko
\paper Crystal and magnetic structures of granular powder spinel Mn--Zn- and Ni--Zn ferrites
\jour Fizika Tverdogo Tela
\yr 2018
\vol 60
\issue 9
\pages 1683--1688
\mathnet{http://mi.mathnet.ru/ftt9070}
\crossref{https://doi.org/10.21883/FTT.2018.09.46384.055}
\elib{https://elibrary.ru/item.asp?id=36903684}
\transl
\jour Phys. Solid State
\yr 2018
\vol 60
\issue 9
\pages 1727--1732
\crossref{https://doi.org/10.1134/S1063783418090020}
Linking options:
https://www.mathnet.ru/eng/ftt9070
https://www.mathnet.ru/eng/ftt/v60/i9/p1683
This publication is cited in the following 4 articles:
Sh.N. Aliyeva, T. R. Mehdiyev, S. H. Jabarov, Kh. N. Ahmadova, I. F. Yusibova, “Temperature Dependences of the Total Spin Moment in Nanopowders of Ni1-xZnxFe2O4 (x = 0.0; 0.25; 0.5; 0.75; 1.0) Ferrospinels”, J Supercond Nov Magn, 36:1 (2023), 367
Robert C. Dickson, Troy D. Manning, Edwin S. Raj, Jonathan C. S. Booth, Matthew J. Rosseinsky, Matthew S. Dyer, “Predicting spinel solid solutions using a random atom substitution method”, Phys. Chem. Chem. Phys., 24:26 (2022), 16374
Preeti Thakur, Shilpa Taneja, Deepika Chahar, Blaise Ravelo, Atul Thakur, “Recent advances on synthesis, characterization and high frequency applications of Ni-Zn ferrite nanoparticles”, Journal of Magnetism and Magnetic Materials, 530 (2021), 167925
Kai Sun, Yaping Li, Shuai Feng, Qizhen Gao, Zongxiang Wang, Xumin Wei, Licheng Ju, Runhua Fan, “Optimizing the Soft Magnetic Properties of Mn-Zn Ferrite by a Proper Control of Sintering Process”, Journal of Elec Materi, 50:3 (2021), 1467