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Fizika Tverdogo Tela, 2018, Volume 60, Issue 10, Pages 1916–1923
DOI: https://doi.org/10.21883/FTT.2018.10.46518.129
(Mi ftt9039)
 

This article is cited in 4 scientific papers (total in 4 papers)

Dielectrics

Experimental study and analysis of absorption spectra of Ni$^{2+}$ ions in nickel orthoborate Ni$_{3}$(BO$_{3}$)$_{2}$

A. D. Molchanova

Institute of Spectroscopy, Russian Academy of Sciences, Troitsk, Moscow
Full-text PDF (366 kB) Citations (4)
Abstract: The results of studies of the absorption spectra of nickel orthoborate Ni$_{3}$(BO$_{3}$)$_{2}$ in the range of electronic $d$$d$-transitions are reported. The obtained data are analyzed in the framework of the crystal field theory. The Ni$^{2+}$ ions are located in two crystallographically nonequivalent positions 2$a$ and 4$f$ with point symmetry groups $C_{2h}$ and $C_{2}$, respectively, surrounded by six oxygen ions forming deformed octahedra. The absorption spectra exhibit three intense bands corresponding to spin-resolved transitions from the ground state of nickel ion $^{3}A_{2g}(^{3}F)$ to the sublevels of the $^{3}T_{2g}(^{3}F)$, $^{3}T_{1g}(^{3}F)$ and $^{3}T_{1g}(^{3}P)$ triplets split by the spinorbit interaction and the rhombic component of the crystal field. At temperatures below 100 K, the spectra exhibit a thin structure, in which phonon-free lines can be distinguished. Comparison of the calculated frequencies of the zero-phonon transitions with the experimental data allows estimating parameters of the crystal field acting on the nickel ions in the 2$a$- and 4$f$-positions, as well as the parameters of electrostatic interaction between the 3$d$ electrons and spin-orbit interaction constants.
Funding agency Grant number
Russian Science Foundation 16-12-10456
Russian Foundation for Basic Research 17-32-50008 мол_нр
Received: 11.05.2018
English version:
Physics of the Solid State, 2018, Volume 60, Issue 10, Pages 1957–1965
DOI: https://doi.org/10.1134/S1063783418100219
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: A. D. Molchanova, “Experimental study and analysis of absorption spectra of Ni$^{2+}$ ions in nickel orthoborate Ni$_{3}$(BO$_{3}$)$_{2}$”, Fizika Tverdogo Tela, 60:10 (2018), 1916–1923; Phys. Solid State, 60:10 (2018), 1957–1965
Citation in format AMSBIB
\Bibitem{Mol18}
\by A.~D.~Molchanova
\paper Experimental study and analysis of absorption spectra of Ni$^{2+}$ ions in nickel orthoborate Ni$_{3}$(BO$_{3}$)$_{2}$
\jour Fizika Tverdogo Tela
\yr 2018
\vol 60
\issue 10
\pages 1916--1923
\mathnet{http://mi.mathnet.ru/ftt9039}
\crossref{https://doi.org/10.21883/FTT.2018.10.46518.129}
\elib{https://elibrary.ru/item.asp?id=36903721}
\transl
\jour Phys. Solid State
\yr 2018
\vol 60
\issue 10
\pages 1957--1965
\crossref{https://doi.org/10.1134/S1063783418100219}
Linking options:
  • https://www.mathnet.ru/eng/ftt9039
  • https://www.mathnet.ru/eng/ftt/v60/i10/p1916
  • This publication is cited in the following 4 articles:
    1. Svetlana Sofronova, Evgeniya Moshkina, Artem Chernyshev, Aleksandr Vasiliev, Nikolai G. Maximov, Aleksandr Aleksandrovsky, Tatyana Andryushchenko, Aleksandr Shabanov, “Crystal growth and cation order of Ni3-xCoxB2O6 oxyborates”, CrystEngComm, 26:19 (2024), 2536  crossref
    2. Mingwei Su, Dapeng Yang, Changlai Yuan, Liufang Meng, Baohua Zhu, Jiwen Xu, Changrong Zhou, Guanghui Rao, “The effect of defects induced by polarization on bandgap evolution and photovoltaic performance in KN-based semiconducting ferroelectric ceramics”, Materials Science in Semiconductor Processing, 165 (2023), 107680  crossref
    3. E.L. Belokoneva, T.A. Eremina, D.G. Koshchug, O.V. Dimitrova, A.S. Volkov, “Cubic Fd3¯c Ba8{Ni,Mn}4[BP3O11(OH)2]4 with anionic units of four-octahedral clusters and four borophosphate groups embedded into Ba-cations medium”, Solid State Sciences, 98 (2019), 106013  crossref
    4. M. A. Prosnikov, A. N. Smirnov, V. Yu. Davydov, Y. Araki, T. Arima, R. V. Pisarev, “Lattice and magnetic dynamics in the polar, chiral, and incommensurate antiferromagnet Ni2InSbO6”, Phys. Rev. B, 100:14 (2019)  crossref
    Citing articles in Google Scholar: Russian citations, English citations
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