Abstract:
Proton magnetic resonance (PMR) spectra and terahertz IR spectra of Vectra A950 fibers and granules and Armos fibers before and after heat treatment were obtained and analyzed in order to understand the molecular mobility mechanisms that ensure the self-organization and restructurization of these rigid-chain liquid-crystal polymers, as well as their similarity and difference. It is shown that large-scale thermal (quasi-segmental) mobility in such LC polymers is due to the reptation of macromolecules with respect to each other and the conformational transitions necessary for the motion of chains in them are the result of random accumulation of displacements that occur during local bending and torsional-vibrational movements in the links of polymer chains according to the Bresler–Frenkel mechanism.
Citation:
V. A. Ryzhov, V. V. Zhizhenkov, N. G. Kvachadze, “Specificities of local dynamics and orientational state of rigid-chain liquid-crystal polymers”, Fizika Tverdogo Tela, 61:2 (2019), 381–387; Phys. Solid State, 61:2 (2019), 249–255
\Bibitem{RyzZhiKva19}
\by V.~A.~Ryzhov, V.~V.~Zhizhenkov, N.~G.~Kvachadze
\paper Specificities of local dynamics and orientational state of rigid-chain liquid-crystal polymers
\jour Fizika Tverdogo Tela
\yr 2019
\vol 61
\issue 2
\pages 381--387
\mathnet{http://mi.mathnet.ru/ftt8932}
\crossref{https://doi.org/10.21883/FTT.2019.02.47141.218}
\elib{https://elibrary.ru/item.asp?id=37478275}
\transl
\jour Phys. Solid State
\yr 2019
\vol 61
\issue 2
\pages 249--255
\crossref{https://doi.org/10.1134/S1063783419020239}
Linking options:
https://www.mathnet.ru/eng/ftt8932
https://www.mathnet.ru/eng/ftt/v61/i2/p381
This publication is cited in the following 2 articles:
Yifei Wu, Kun Wu, Fei Xiao, Wenjie Diao, Daguang He, Hui Yang, Jun Shi, “High Thermal Conductivity and Low Dielectric Constant of Polyesters Based on Fluorine and Mesogenic Unit”, Macro Chemistry & Physics, 224:19 (2023)
S. M. Shebanov, V. B. Ivanov, A. V. Pavlikov, M. S. Shebanov, V. G. Bova, I. G. Kalinina, I. K. Novikov, L. B. Shiyanova, “Effect of Treatment of the Surface of Para-Aramid Fiber with Multiwall Carbon Nanotubes on Its Structure and Properties. Infrared Spectra”, Fibre Chem, 53:4 (2021), 283