Abstract:
The structure, the photoluminescence, and IR absorption spectra of solid solutions (Lu1−xEux)2(MoO4)3 have been studied over a wide range of europium concentrations (0⩽x⩽1). It has been found that there is a correlation between the structure and the spectral characteristics of these compounds. Three types of crystal phases are sequentially changed as the europium concentration increases. The photoluminescence and IR absorption spectra of the monoclinic phase with space group P21/a have been studied for the first time. The glow maximum at a resonant excitation of Eu3+ ions is shown to be observed in the samples with orthorhombic structure Pba 2 at x∼ 0.8. The samples existing in monoclinic P21/a phase at x∼ 0.2 demonstrate the maximum luminescence intensity upon excitation in the band with the charge transfer.
Citation:
S. Z. Shmurak, V. V. Kedrov, A. P. Kiselev, T. N. Fursova, I. I. Zver'kova, S. S. Khasanov, “Spectral and structural characteristics of molybdates (Lu1−xEux)2(MoO4)3”, Fizika Tverdogo Tela, 61:4 (2019), 747–756; Phys. Solid State, 61:4 (2019), 632–641
\Bibitem{ShmKedKis19}
\by S.~Z.~Shmurak, V.~V.~Kedrov, A.~P.~Kiselev, T.~N.~Fursova, I.~I.~Zver'kova, S.~S.~Khasanov
\paper Spectral and structural characteristics of molybdates (Lu$_{1-x}$Eu$_{x}$)$_{2}$(MoO$_{4}$)$_{3}$
\jour Fizika Tverdogo Tela
\yr 2019
\vol 61
\issue 4
\pages 747--756
\mathnet{http://mi.mathnet.ru/ftt8865}
\crossref{https://doi.org/10.21883/FTT.2019.04.47425.324}
\elib{https://elibrary.ru/item.asp?id=37645625}
\transl
\jour Phys. Solid State
\yr 2019
\vol 61
\issue 4
\pages 632--641
\crossref{https://doi.org/10.1134/S1063783419040280}
Linking options:
https://www.mathnet.ru/eng/ftt8865
https://www.mathnet.ru/eng/ftt/v61/i4/p747
This publication is cited in the following 12 articles:
S. V. Zaitsev, “Luminescence kinetics of Eu<sup>3+</sup> ions in tungstates (Lu<sub>1 – x</sub>Eu<sub>x</sub>)<sub>2</sub>(WO<sub>4</sub>)<sub>3</sub> and molybdates (Lu<sub>1 – x</sub>Eu<sub>x</sub>)<sub>2</sub>(MoO<sub>4</sub>)<sub>3</sub>”, Izvestiya Rossiiskoi akademii nauk. Seriya fizicheskaya, 87:2 (2023), 208
Ivan da Silva, Gerardo Gil de Cos, Cristina González-Silgo, Javier López-Solano, Andrés Mujica, Nivaria R. Ramírez-Rodríguez, Manuel E. Torres, “Solid-State Synthesis and Phase Transitions in the RE2(MoO4)3 Family Monitored by Thermodiffraction”, Crystal Growth & Design, 23:4 (2023), 2417
S. V. Zaitsev, “Luminescence Kinetics of Eu3+ Ions in (Lu1 – xEux)2(WO4)3 Tungstates and (Lu1 – xEux)2(MoO4)3 Molybdates”, Bull. Russ. Acad. Sci. Phys., 87:2 (2023), 178
Mikhail S. Grigoriev, Iraida A. Charushnikova, Nina A. Budantseva, Alexander M. Fedoseev, “Mixed-Valence NpV/AnVI Molybdate Complexes with Single-Charge Outer-Sphere Cations”, Inorg. Chem., 62:32 (2023), 12708
O N Bugaets, E A Kaygorodova, I A Bugaets, N E Kosyanok, N A Bugaets, “Synthesis, structure and luminescent properties of co-precipitated europium and aluminum hydroxides”, IOP Conf. Ser.: Earth Environ. Sci., 1076:1 (2022), 012040
Gerardo Gil de Cos, M.E. Torres, C. González-Silgo, Kevin Soler-Carracedo, Inocencio R. Martín, F. Rivera-López, S. Rodríguez-Rodríguez, “Unexpected Wide Tuning of Ferroelectric Properties by Varying the Er Concentration in La2-Xerx(Moo4)3 (X = 0.75, 1, 1.25) Solid Solutions”, SSRN Journal, 2022
G. Gil-de-Cos, M.E. Torres, C. González-Silgo, K. Soler-Carracedo, I.R. Martín, F. Rivera-López, S. Rodríguez-Rodríguez, “Unexpected wide tuning of ferroelectric properties by varying the Er concentration in La2-xErx(MoO4)3 (x = 0.75, 1, 1.25) solid solutions”, Journal of Solid State Chemistry, 315 (2022), 123462
V.V. Popov, A.P. Menushenkov, A.A. Yastrebtsev, A.Yu. Molokova, S.G. Rudakov, R.D. Svetogorov, N.A. Tsarenko, K.V. Ponkratov, N.V. Ognevskaya, O.N. Seregina, “The effect of the synthesis conditions on the structure and phase transitions in Ln2(MoO4)3”, Solid State Sciences, 112 (2021), 106518
Zhongxiang Shi, Jing Wang, Jun Shi, Tongyu Meng, Yang Lu, “Temperature characteristics of NaY(MoO4)2: Sm3+ and effect of Li+ doping on luminescent properties of phosphors”, J Mater Sci: Mater Electron, 32:21 (2021), 26086
S. Z. Shmurak, V. V. Kedrov, A. P. Kiselev, T. N. Fursova, I. I. Zver'kova, E. Yu. Postnova, “The peculiarities of the spectral characteristics of different Lu1−xRExBO3 structural modifications”, Phys. Solid State, 63:12 (2021), 1795–1810
S. Z. Shmurak, V. V. Kedrov, A. P. Kiselev, T. N. Fursova, I. I. Zver'kova, S. S. Khasanov, “Influence of cerium on the spectral and structural characteristics of LuBO3(Ce, Tb)”, Phys. Solid State, 62:11 (2020), 2122–2131
S. Z. Shmurak, V. V. Kedrov, A. P. Kiselev, T. N. Fursova, I. I. Zver'kova, S. S. Khasanov, “Spectral and structural characteristics of (Lu1−xEux)2(WO4)3 tungstates”, Phys. Solid State, 61:11 (2019), 2117–2129
Citation in format AMSBIB
Contact us: