Abstract:
An analysis of primary literature sources shows that there is only one reliable report on the observation of the cubic ZrO2 phase by the X-ray method under oxidizing conditions. This phase is observed at temperatures not lower than 2500∘C. All other reports on the observation of a phase transition around 2300∘C are reliable only in relation to the existence of a transition at this temperature, but this transition is to the t' tetragonal phase rather than to the cubic one. The conclusion is that the following four polymorphic modifications are present in ZrO2 under the standard pressure: monoclinic (m), two tetragonal (t and t'), and cubic (c) phases that are converted into each other with an increase in the temperature.
Citation:
V. P. Gorelov, “The high-temperature polymorphism of ZrO2”, Fizika Tverdogo Tela, 61:7 (2019), 1346–1351; Phys. Solid State, 61:7 (2019), 1288–1293
\Bibitem{Gor19}
\by V.~P.~Gorelov
\paper The high-temperature polymorphism of ZrO$_{2}$
\jour Fizika Tverdogo Tela
\yr 2019
\vol 61
\issue 7
\pages 1346--1351
\mathnet{http://mi.mathnet.ru/ftt8765}
\crossref{https://doi.org/10.21883/FTT.2019.07.47849.383}
\elib{https://elibrary.ru/item.asp?id=41130008}
\transl
\jour Phys. Solid State
\yr 2019
\vol 61
\issue 7
\pages 1288--1293
\crossref{https://doi.org/10.1134/S1063783419070096}
Linking options:
https://www.mathnet.ru/eng/ftt8765
https://www.mathnet.ru/eng/ftt/v61/i7/p1346
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