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Fizika Tverdogo Tela, 2019, Volume 61, Issue 7, Pages 1346–1351
DOI: https://doi.org/10.21883/FTT.2019.07.47849.383
(Mi ftt8765)
 

This article is cited in 16 scientific papers (total in 16 papers)

Phase transitions

The high-temperature polymorphism of ZrO$_{2}$

V. P. Gorelov

Institute of High-Temperature Electrochemistry, RAS, Yekaterinburg, Russia
Abstract: An analysis of primary literature sources shows that there is only one reliable report on the observation of the cubic ZrO$_{2}$ phase by the X-ray method under oxidizing conditions. This phase is observed at temperatures not lower than 2500$^\circ$C. All other reports on the observation of a phase transition around 2300$^\circ$C are reliable only in relation to the existence of a transition at this temperature, but this transition is to the $t$' tetragonal phase rather than to the cubic one. The conclusion is that the following four polymorphic modifications are present in ZrO$_{2}$ under the standard pressure: monoclinic $(m)$, two tetragonal ($t$ and $t$'), and cubic $(c)$ phases that are converted into each other with an increase in the temperature.
Funding agency Grant number
Russian Foundation for Basic Research 17-08-01227
This work was partly supported by the Russian Foundation for Basic Research (grant no. 17-08-01227).
Received: 21.02.2019
Revised: 12.03.2019
Accepted: 12.03.2019
English version:
Physics of the Solid State, 2019, Volume 61, Issue 7, Pages 1288–1293
DOI: https://doi.org/10.1134/S1063783419070096
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: V. P. Gorelov, “The high-temperature polymorphism of ZrO$_{2}$”, Fizika Tverdogo Tela, 61:7 (2019), 1346–1351; Phys. Solid State, 61:7 (2019), 1288–1293
Citation in format AMSBIB
\Bibitem{Gor19}
\by V.~P.~Gorelov
\paper The high-temperature polymorphism of ZrO$_{2}$
\jour Fizika Tverdogo Tela
\yr 2019
\vol 61
\issue 7
\pages 1346--1351
\mathnet{http://mi.mathnet.ru/ftt8765}
\crossref{https://doi.org/10.21883/FTT.2019.07.47849.383}
\elib{https://elibrary.ru/item.asp?id=41130008}
\transl
\jour Phys. Solid State
\yr 2019
\vol 61
\issue 7
\pages 1288--1293
\crossref{https://doi.org/10.1134/S1063783419070096}
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  • https://www.mathnet.ru/eng/ftt/v61/i7/p1346
  • This publication is cited in the following 16 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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