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This article is cited in 16 scientific papers (total in 16 papers)
Phase transitions
The high-temperature polymorphism of ZrO$_{2}$
V. P. Gorelov Institute of High-Temperature Electrochemistry, RAS, Yekaterinburg, Russia
Abstract:
An analysis of primary literature sources shows that there is only one reliable report on the observation of the cubic ZrO$_{2}$ phase by the X-ray method under oxidizing conditions. This phase is observed at temperatures not lower than 2500$^\circ$C. All other reports on the observation of a phase transition around 2300$^\circ$C are reliable only in relation to the existence of a transition at this temperature, but this transition is to the $t$' tetragonal phase rather than to the cubic one. The conclusion is that the following four polymorphic modifications are present in ZrO$_{2}$ under the standard pressure: monoclinic $(m)$, two tetragonal ($t$ and $t$'), and cubic $(c)$ phases that are converted into each other with an increase in the temperature.
Received: 21.02.2019 Revised: 12.03.2019 Accepted: 12.03.2019
Citation:
V. P. Gorelov, “The high-temperature polymorphism of ZrO$_{2}$”, Fizika Tverdogo Tela, 61:7 (2019), 1346–1351; Phys. Solid State, 61:7 (2019), 1288–1293
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https://www.mathnet.ru/eng/ftt8765 https://www.mathnet.ru/eng/ftt/v61/i7/p1346
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