Abstract:
For the first time, the Sr2La8−xTmx(GeO4)6O2 (x = 0.1 – 1.0) solid solution with the apatite structure were synthesized by the solid-phase method, and their spectral–luminescence properties were studied. The prospects of using these compounds as phosphors in the visible and short-wave infrared ranges were demonstrated. The luminescence of Sr2La8−xTmx(GeO4)6O2 germanates, which occurs under ultraviolet radiation, is characterized by the high purity of blue color; the chromaticity coordinates are close to commercially available phosphors. The
Sr2La8−xTmx(GeO4)6O2 compounds efficiently convert 808 nm laser radiation into a series of emission lines in the 1.3 – 2.2 μm spectral range, caused by sequential 3H4→3F4 и 3F4→3H6 transitions in Tm3+ ions. Germanate Sr2La8−xTmx(GeO4)6O2 with a maximum emission intensity in the short-wave infrared region shows high thermal stability of luminescence in the 30–220∘C range.
Keywords:
germanate, apatite, luminescence, thulium, short-wave IR range.
Citation:
Ya. V. Baklanova, O. A. Lipina, L. L. Surat, A. Yu. Chufarov, A. P. Tyutyunnik, V. G. Zubkov, “Luminescence properties of Sr2La8−xTmx(GeO4)6O2 apatites (x = 0.1 – 1.0) in the visible and short-wave ir spectral ranges”, Fizika Tverdogo Tela, 62:8 (2020), 1252–1259; Phys. Solid State, 62:8 (2020), 1407–1414