Abstract:
For the first time, the Sr2La8−xTmx(GeO4)6O2 (x = 0.1 – 1.0) solid solution with the apatite structure were synthesized by the solid-phase method, and their spectral–luminescence properties were studied. The prospects of using these compounds as phosphors in the visible and short-wave infrared ranges were demonstrated. The luminescence of Sr2La8−xTmx(GeO4)6O2 germanates, which occurs under ultraviolet radiation, is characterized by the high purity of blue color; the chromaticity coordinates are close to commercially available phosphors. The
Sr2La8−xTmx(GeO4)6O2 compounds efficiently convert 808 nm laser radiation into a series of emission lines in the 1.3 – 2.2 μm spectral range, caused by sequential 3H4→3F4 и 3F4→3H6 transitions in Tm3+ ions. Germanate Sr2La8−xTmx(GeO4)6O2 with a maximum emission intensity in the short-wave infrared region shows high thermal stability of luminescence in the 30–220∘C range.
Keywords:
germanate, apatite, luminescence, thulium, short-wave IR range.
Citation:
Ya. V. Baklanova, O. A. Lipina, L. L. Surat, A. Yu. Chufarov, A. P. Tyutyunnik, V. G. Zubkov, “Luminescence properties of Sr2La8−xTmx(GeO4)6O2 apatites (x = 0.1 – 1.0) in the visible and short-wave ir spectral ranges”, Fizika Tverdogo Tela, 62:8 (2020), 1252–1259; Phys. Solid State, 62:8 (2020), 1407–1414
\Bibitem{BakLipSur20}
\by Ya.~V.~Baklanova, O.~A.~Lipina, L.~L.~Surat, A.~Yu.~Chufarov, A.~P.~Tyutyunnik, V.~G.~Zubkov
\paper Luminescence properties of Sr$_{2}$La$_{8-x}$Tm$_{x}$(GeO$_{4}$)$_{6}$O$_{2}$ apatites ($x$ = 0.1 -- 1.0) in the visible and short-wave ir spectral ranges
\jour Fizika Tverdogo Tela
\yr 2020
\vol 62
\issue 8
\pages 1252--1259
\mathnet{http://mi.mathnet.ru/ftt8349}
\crossref{https://doi.org/10.21883/FTT.2020.08.49610.045}
\elib{https://elibrary.ru/item.asp?id=43818066}
\transl
\jour Phys. Solid State
\yr 2020
\vol 62
\issue 8
\pages 1407--1414
\crossref{https://doi.org/10.1134/S1063783420080053}
Linking options:
https://www.mathnet.ru/eng/ftt8349
https://www.mathnet.ru/eng/ftt/v62/i8/p1252
This publication is cited in the following 5 articles:
Olga A Lipina, Yana V Baklanova, Ilya S Popov, Lyudmila L Surat, Alexander Yu Chufarov, Alexander P Tyutyunnik, Anna A Rybnikova, Vladimir G Zubkov, “Structural and spectroscopic characterization of Ba3RE2(Ge3O9)2 (RE = La, Pr, Nd) and Ba3La2-
xEux(Ge3O9)2 cyclogermanates”, J. Phys. D: Appl. Phys., 58:9 (2025), 095302
Anna A. Melentsova, Olga A. Lipina, Marina A. Melkozerova, Andrey N. Enyashin, Alexander Yu Chufarov, Alexander P. Tyutyunnik, Vladimir G. Zubkov, “Infrared luminescence properties and energy transfer mechanism in NaYGeO4:Tm3+ powders”, Ceramics International, 50:11 (2024), 18681
Anna A. Melentsova, Olga A. Lipina, Alexander Yu. Chufarov, Alexander P. Tyutyunnik, Vladimir G. Zubkov, “Microwave-assisted synthesis and luminescence properties of NaYb1-xErxGeO4, NaY1-yYb3y/4Ery/4GeO4 olivines”, Journal of Solid State Chemistry, 322 (2023), 123946
Ivan V. Nikiforov, Dina V. Deyneko, Dmitry A. Spassky, Bogdan I. Lazoryak, Sergey M. Aksenov, “Whitlockite-Type Structure as a Matrix for Optical Materials: Synthesis and Characterization of Novel TM-SM Co-Doped Phosphate Ca9Gd(PO4)7, a Single-Phase White Light Phosphors”, Minerals, 12:1 (2022), 76
Ya.V. Baklanova, O. A. Lipina, A. Yu. Chufarov, L. L. Surat, A. P. Tyutyunnik, D. G. Kellerman, V. G. Zubkov, “Crystal structure, infrared luminescence and magnetic properties of Tm3+-doped and Tm3+-, Dy3+-codoped BaY2Ge3O10 germanates”, J Mater Sci: Mater Electron, 32:11 (2021), 14976