Abstract:
Trigonal single crystals of neodymium scandoborate NdSc3(BO3)4 were grown by the group method from a melt-solution based on bismuth trimolybdate. Its magnetic and magnetoelectric properties have been studied in the temperature range 4.2–300 K and in magnetic fields up to 9 T. Magnetically, it is a paramagnet, the properties of which are determined by the magnetic properties of the Nd3+ ion taking into account the Van Vleck paramagnetic correction. The magnitude of the magnetoelectric polarization turned out to be comparable with the previously investigated diluted neodymium alumoborate Nd0.35Y0.65Al3(BO3)4. This circumstance opens up one more subclass of compounds in which a giant magnetoelectric effect should be observed.
This study was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk krai, and the Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project no. 18-42-240011 “Development of the Flux Techniques for Growing New Scandoborate Single Crystals with a Huntite Structure and Study of the Interaction of Their Magnetic and Electric Subsystems”.
Citation:
E. V. Eremin, A. A. Doubrovskii, I. A. Gudim, V. R. Titova, M. V. Merkulov, “Magnetic and magnetoelectric properties of scandoborate NdSc3(BO3)4”, Fizika Tverdogo Tela, 63:7 (2021), 911–914; Phys. Solid State, 63:6 (2021), 968–971
\Bibitem{EreDouGud21}
\by E.~V.~Eremin, A.~A.~Doubrovskii, I.~A.~Gudim, V.~R.~Titova, M.~V.~Merkulov
\paper Magnetic and magnetoelectric properties of scandoborate NdSc$_{3}$(BO$_{3}$)$_{4}$
\jour Fizika Tverdogo Tela
\yr 2021
\vol 63
\issue 7
\pages 911--914
\mathnet{http://mi.mathnet.ru/ftt8094}
\crossref{https://doi.org/10.21883/FTT.2021.07.51041.042}
\elib{https://elibrary.ru/item.asp?id=46346440}
\transl
\jour Phys. Solid State
\yr 2021
\vol 63
\issue 6
\pages 968--971
\crossref{https://doi.org/10.1134/S1063783421070052}
Linking options:
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This publication is cited in the following 1 articles:
A.V. Malakhovskii, V.V. Sokolov, A.L. Sukhachev, I.A. Gudim, “Magnetic circular dichroism of f-f electron transitions in Ho3+ and Nd3+ ions in antiferromagnetic crystal Ho0.75Nd0.25Fe3(BO3)4 in the region of spin-reorientation transition”, Journal of Magnetism and Magnetic Materials, 2024, 172613