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This article is cited in 1 scientific paper (total in 1 paper)
Impurity centers
Wideband epr spectroscopy of Tb$^{3+}$ and Fe$^{2+}$ ions in YAlO$_{3}$ single crystals
G. R. Asatryana, G. S. Shakurovb, I. V. Il'ina, A. G. Petrosyanc, K. L. Ovanesyana, M. V. Derdzyanc a Ioffe Institute, St. Petersburg, Russia
b Zavoisky Physical Technical Institute, Kazan Scientific Center of the Russian Academy of Sciences, Kazan'
c Institute for Physical Research NAS of Armenia, Ashtarak-2, Armenia
Abstract:
An iron-doped YAlO$_{3}$ crystal was studied by wideband EPR spectroscopy. Two types of paramagnetic centers have been found. The energy scheme of the levels of one of them is a singlet and a doublet with a splitting between them of 215.2 GHz. This center is presumably due to the Fe$^{2+}$ ion. The second center was identified as a Tb$^{3+}$ ion that entered the crystal as a trace impurity. For each case, the localization of the impurity ion in the YAlO$_{3}$ crystal lattice is determined. Within the framework of the existing theory, calculations were made and spectral parameters were determined.
Keywords:
broadband electron paramagnetic resonance, yttrium orthoaluminate, impurity centers, non-Kramers ions.
Received: 28.05.2021 Revised: 28.05.2021 Accepted: 02.06.2021
Citation:
G. R. Asatryan, G. S. Shakurov, I. V. Il'in, A. G. Petrosyan, K. L. Ovanesyan, M. V. Derdzyan, “Wideband epr spectroscopy of Tb$^{3+}$ and Fe$^{2+}$ ions in YAlO$_{3}$ single crystals”, Fizika Tverdogo Tela, 63:10 (2021), 1612–1616; Phys. Solid State, 63:12 (2021), 1879–1883
Linking options:
https://www.mathnet.ru/eng/ftt7998 https://www.mathnet.ru/eng/ftt/v63/i10/p1612
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