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Continued publication of the materials of the seminar in FTT N 12/21
Impurity centers
Effect of the defectiveness of the carbon sublattice on the elastic properties of cubic titanium carbide TiC$_{y}$
A. I. Gusev Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences, Yekaterinburg, Russia
Abstract:
Changes in the elastic constants c$_{ij}$ of disordered cubic titanium carbide TiC$_{y}$ with an increasing the defectiveness of the carbon sublattice are estimated for the first time. It was found that the deviation of titanium carbide from the stoichiometric composition TiC$_{1.0}$ leads to a decrease in the elastic stiffness constants c$_{ij}$ of disordered TiC$_{y}$ carbide with a simultaneous increase in elastic anisotropy. The distributions of Young's modulus $E$ and Poisson's ratio $\mu$ in the (100) plane and the distributions of the shear modulus $G$ in the (100), (110), and (111) planes have been calculated as functions on the crystallographic direction $[hkl]$ and on the relative carbon content $y$ in TiC$_{y}$ carbide. The lowest values of the shear modulus G$_{hkl}$ for TiC$_{y}$ are observed in the (111) plane.
Keywords:
titanium carbide, nonstoichiometry, vacancies, elastic properties.
Received: 18.06.2021 Revised: 18.06.2021 Accepted: 22.06.2021
Citation:
A. I. Gusev, “Effect of the defectiveness of the carbon sublattice on the elastic properties of cubic titanium carbide TiC$_{y}$”, Fizika Tverdogo Tela, 63:11 (2021), 1921–1926
Linking options:
https://www.mathnet.ru/eng/ftt7969 https://www.mathnet.ru/eng/ftt/v63/i11/p1921
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Statistics & downloads: |
Abstract page: | 77 | Full-text PDF : | 33 |
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