Abstract:
A series of co-doped KSrPO$_4$:Eu$^{2+}$ , Y$^{3+}$ phosphors have been prepared through a high-temperature solid-state reaction at various temperatures. Luminescence spectroscopic characterization allowed to demonstrate that emission spectrum of original KSrPO$_4$:Eu$^{2+}$ phosphor that is typically dominated by Eu$^{2+}4f^65d^1\to4f^7$ emission can be significantly modified by co-doping with Y$^{3+}$ ions, which results in appearance of a broad defect emission. The latter makes the phosphor potential for WLED application. The Y$^{3+}$ co-doping related defect emission was found to get enhanced with the increase of Y$^{3+}$ content and synthesis temperature. The nature and peculiarities of the new defect emission are discussed.
This work was financially supported by the Natural Science Foundation of Shanxi Province (201801D121020 and 201801D221132) and Key Research and Development (R&D) Projects of Shanxi Province (201903D121097). K.V.I. acknowledges partial support from Ministry of Science and Higher Education of the Russian Federation (Project no. FEUZ-2020-0060).
Citation:
X. Geng, L. Wang, Q. Shi, K. V. Ivanovskikh, H. Guo, C. Cui, P. Huang, “Tuning emission spectrum of KSrPO$_4$:Eu$^{2+}$ phosphor by co-doping with Y$^{3+}$”, Fizika Tverdogo Tela, 63:6 (2021), 796; Phys. Solid State, 63:6 (2021), 832–838
\Bibitem{GenWanShi21}
\by X.~Geng, L.~Wang, Q.~Shi, K.~V.~Ivanovskikh, H.~Guo, C.~Cui, P.~Huang
\paper Tuning emission spectrum of KSrPO$_4$:Eu$^{2+}$ phosphor by co-doping with Y$^{3+}$
\jour Fizika Tverdogo Tela
\yr 2021
\vol 63
\issue 6
\pages 796
\mathnet{http://mi.mathnet.ru/ftt10145}
\transl
\jour Phys. Solid State
\yr 2021
\vol 63
\issue 6
\pages 832--838
\crossref{https://doi.org/10.1134/S1063783421060081}
Linking options:
https://www.mathnet.ru/eng/ftt10145
https://www.mathnet.ru/eng/ftt/v63/i6/p796
This publication is cited in the following 1 articles:
Yan Xiang, Hancheng Zhu, Pengpeng Dai, Meng Zhang, “Ultra-broadband emission up to 181 nm of VO4-activated yellow phosphor for white light-emitting diodes with high color rendering index”, Journal of Luminescence, 267 (2024), 120397