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Optical properties
Synthesis and Luminescence of Ba$_2$ScCl$_7$
R. A. Bhoyara, A. C. Nayaka, S. P. Wankhedeb, P. D. Belsarec, S. V. Moharild a RKDF University, Bhopal, India
b Department of Physics, K.D.K. College of Engineering,
Nagpur, India
c Shri Ramdeobaba College of Engineering and Management,
Nagpur, 440013, India
d Department of Physics, RTM Nagpur University,
Nagpur, 440033, India
Abstract:
New results on luminescence in Ba$_2$ScCl$_7$ are reported. Lanthanides Eu$^{2+}$ and Ce$^{3+}$ were chosen as activators. The phosphors could be prepared by a simple wet chemical method. Reduction of europium to the divalent form could be achieved at 400$^\circ$C. Both activators exhibit strong photoluminescence (PL) originating in transitions from the lowest energy state of
4f$^{n-1}$15d$^1$ configuration to the ground state of 4f$^7$/4f$^1$ configuration. Simple preparation coupled with intense PL prompted us to suggest that these hitherto unexplored phosphors could be exploited for applications such as scintillator.
Keywords:
halide, photoluminescence, phosphor.
Received: 24.02.2021 Revised: 02.03.2021 Accepted: 03.03.2021
Citation:
R. A. Bhoyar, A. C. Nayak, S. P. Wankhede, P. D. Belsare, S. V. Moharil, “Synthesis and Luminescence of Ba$_2$ScCl$_7$”, Fizika Tverdogo Tela, 63:7 (2021), 951; Phys. Solid State, 63:6 (2021), 948–952
Linking options:
https://www.mathnet.ru/eng/ftt10142 https://www.mathnet.ru/eng/ftt/v63/i7/p951
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Abstract page: | 62 | Full-text PDF : | 12 |
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