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Fizika Tverdogo Tela, 2016, Volume 58, Issue 1, Pages 163–169 (Mi ftt10125)  

This article is cited in 22 scientific papers (total in 22 papers)

Optical properties

Raman scattering in sodium nitrite crystals near the phase transition

V. S. Gorelika, A. Yu. Pyatyshevb, A. S. Krylovc

a P. N. Lebedev Physical Institute of the Russian Academy of Sciences, Moscow
b Bauman Moscow State Technical University
c L. V. Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk
Abstract: Optical Raman spectra of a ferroelectric sodium nitrite crystal have been detected in a wide spectrum range at various temperatures, including the region of the ferroelectric phase transition. A manifestation of a transverse soft polar mode of the A1(z) type responsible for the ferroelectric phase transition has been discovered in the spectrum at room temperature. This mode has been found to become overdamped even far from the ferroelectric phase transition temperature. This mode also appears as a central peak under heating. It has been found that the pseudoscalar mode of the A2 type has the highest intensity in the Raman spectrum of sodium nitrite. The frequency corresponding to the maximum intensity of this mode in the Raman spectrum varies from 130 cm1 at 123 K to 106 cm1 at T = 513 K. A fair agreement of the experimental data for the A1(z) mode with the Lyddane–Sachs–Teller relation has been established. The polariton curves for the A1(z) polar mode and the dispersion curves for axinons has been plotted.
Keywords: Raman Spectrum, Dispersion Curve, Polar Mode, Sodium Nitrite, Soft Mode.
Received: 22.06.2015
English version:
Physics of the Solid State, 2016, Volume 58, Issue 1, Pages 170–176
DOI: https://doi.org/10.1134/S1063783416010133
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: V. S. Gorelik, A. Yu. Pyatyshev, A. S. Krylov, “Raman scattering in sodium nitrite crystals near the phase transition”, Fizika Tverdogo Tela, 58:1 (2016), 163–169; Phys. Solid State, 58:1 (2016), 170–176
Citation in format AMSBIB
\Bibitem{GorPyaKry16}
\by V.~S.~Gorelik, A.~Yu.~Pyatyshev, A.~S.~Krylov
\paper Raman scattering in sodium nitrite crystals near the phase transition
\jour Fizika Tverdogo Tela
\yr 2016
\vol 58
\issue 1
\pages 163--169
\mathnet{http://mi.mathnet.ru/ftt10125}
\elib{https://elibrary.ru/item.asp?id=25668767}
\transl
\jour Phys. Solid State
\yr 2016
\vol 58
\issue 1
\pages 170--176
\crossref{https://doi.org/10.1134/S1063783416010133}
Linking options:
  • https://www.mathnet.ru/eng/ftt10125
  • https://www.mathnet.ru/eng/ftt/v58/i1/p163
  • This publication is cited in the following 22 articles:
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    3. H. Yurtseven, O. Akay Sefer, “Calculation of the order parameter and dielectric susceptibility under the electric field near the incommensurate phase in NaNO 2 using Landau model”, Philosophical Magazine, 2024, 1  crossref
    4. Vanessa M. Breslin, Elizabeth S. Ryland, Daniel C. Ratchford, Adam D. Dunkelberger, Tara J. Michael, Jeffrey C. Owrutsky, “Rapid vibrational relaxation dynamics and strong Solute-Solvent interactions of the nitrite anion”, Chemical Physics Letters, 812 (2023), 140265  crossref
    5. V.S. Gorelik, A.Yu. Pyatyshev, “Raman scattering from the effective soft mode in lead germanate crystal”, J Raman Spectroscopy, 51:6 (2020), 969  crossref
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    20. V S Gorelik, V M Korshunov, A I Vodchits, Yu P Voinov, A A Loboyko, “Combinational processes in uranil structures”, J. Phys.: Conf. Ser., 918 (2017), 012047  crossref
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