Effect of phase stratification into electro- and magnetotransport in heteroepitaxial La$_{2/3}$Ca$_{1/3}$MnO$_{3}$ films

The La$_{2/3}$Ca$_{1/3}$MnO$_{3}$ films 25-nm thick biaxially compressed in the substrate plane, grown quasi-coherently on the (001) surface of the LaAlO$_3$ single crystal, were studied using laser vaporization. It was found that mechanical stresses acting during nucleation and growth promoted calcium enrichment of the cation sublattice of the manganite layer, which caused a decrease in its unit cell volume. Crystalline grains in manganite films were distinctly oriented along the normal to the substrate plane; the grain size in the substrate plane was within 20–40 nm, and the relative grain misorientation in the substrate plane did not exceed 0.2$^\circ$. In zero magnetic field, the maximum in the temperature dependence of the resistivity $\rho$ of La$_{2/3}$Ca$_{1/3}$MnO$_{3}$ films was observed at temperatures close to 210 K. At $T<$ 100 K and $\mu_{0}H$ = 2 T, the magnetoresistance of manganite films was negative, weakly depended on temperature, its value was about–0.45. The magnetic field caused transformation of nonferromagnetic phase inclusions to ferromagnetic ones, which resulted in a decrease in the La$_{2/3}$Ca$_{1/3}$MnO$_{3}$ film resistivity with increasing magnetic field. At low temperatures ($T<$ 100 K), a hysteresis was observed in the dependences of the film resistivity on the magnetic field.