A. A. Valeeva, S. Z. Nazarova, A. A. Rempel, “Influence of particle size, stoichiometry, and degree of long-range order on magnetic susceptibility of titanium monoxide”, Fizika Tverdogo Tela, 58:4 (2016), 747–753; Phys. Solid State, 58:4 (2016), 771

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Fizika Tverdogo Tela, 2016, Volume 58, Issue 4, Pages 747–753 (Mi ftt10022)

This article is cited in 17 scientific papers (total in 17 papers)

Low dimensional systems

Influence of particle size, stoichiometry, and degree of long-range order on magnetic susceptibility of titanium monoxide

A. A. Valeeva, S. Z. Nazarova, A. A. Rempel

Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences, Ekaterinburg

Full-text PDF (219 kB) Citations (17)

Abstract: In situ measurements of the magnetic susceptibility of ordered and disordered titanium monoxides TiO$_{y}$ in the temperature range from 300 to 1200 K have revealed that it depends on the size of crystals, their stoichiometry, and long-range order parameters. Analysis of the data for both the ordered and disordered TiO$_{y}$ has demonstrated that the dependence of the Van Vleck paramagnetism on the nanocrystal size is inversely proportional due to the breaking of symmetry of the local environment of titanium and oxygen atoms near the surface of nanocrystals. It has been found that the Van Vleck contribution from the atomic vacancy disorder in monoxide nanocrystals of superstoichiometric composition, as well as in the crystalline stoichiometric monoxide, is proportional to the deviation of the degree of long-range order from the maximum value.

Keywords: Magnetic Susceptibility, Netic Susceptibility, Nanocrystal Size, Superstructure Reflection, Range Order Parameter.

Received: 08.09.2015

English version:
Physics of the Solid State, 2016, Volume 58, Issue 4, Pages 771–778
DOI: https://doi.org/10.1134/S1063783416040284

Bibliographic databases:

Document Type: Article

Language: Russian

Citation: A. A. Valeeva, S. Z. Nazarova, A. A. Rempel, “Influence of particle size, stoichiometry, and degree of long-range order on magnetic susceptibility of titanium monoxide”, Fizika Tverdogo Tela, 58:4 (2016), 747–753; Phys. Solid State, 58:4 (2016), 771–778

Citation in format AMSBIB

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\jour Phys. Solid State

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Linking options:

https://www.mathnet.ru/eng/ftt10022

https://www.mathnet.ru/eng/ftt/v58/i4/p747

This publication is cited in the following 17 articles:

Xiaodan Chen, Seyed Naveed Hosseini, Marijn A. van Huis, “Heating-Induced Transformation of Anatase TiO2 Nanorods into Rock-Salt TiO Nanoparticles: Implications for Photocatalytic and Gas-Sensing Applications”, ACS Appl. Nano Mater., 5:1 (2022), 1600
A. A. Valeeva, A. A. Rempel, S. V. Rempel', S. I. Sadovnikov, A. I. Gusev, “Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides”, Russian Chem. Reviews, 90:5 (2021), 601–626
S.V. Rempel, D.A. Eselevich, H. Schroettner, A.A. Valeeva, A.A. Rempel, “Thermal behaviour of TiOy/HAp nanocomposites”, Ceramics International, 47:7 (2021), 9613
M.I. Chebanenko, D.P. Danilovich, A.A. Lobinsky, V.I. Popkov, A.A. Rempel, A.A. Valeeva, “Novel high stable electrocatalyst based on non-stoichiometric nanocrystalline niobium carbide toward effective hydrogen evolution”, International Journal of Hydrogen Energy, 46:32 (2021), 16907
A. I. Gusev, “High-energy ball milling of nonstoichiometric compounds”, Phys. Usp., 63:4 (2020), 342–364
Albina A. Valeeva, Svetlana Z. Nazarova, Hartmuth Schröttner, Evgeny Yu. Gerasimov, Andrey A. Rempel, “Effects of high mechanical treatment and long-term annealing on crystal structure and thermal stability of Ti2O3 nanocrystals”, RSC Adv., 10:43 (2020), 25717
Albina A. Valeeva, Svetlana Z. Nazarova, Andrey A. Rempel, “Nanosize effect on phase transformations of titanium oxide Ti2O3”, Journal of Alloys and Compounds, 817 (2020), 153215
Maxim G. Kostenko, Albina A. Valeeva, “Disorder–order phase transition in nanocrystalline titanium monoxide with two-sublattice ordering of structural vacancies”, Mendeleev Communications, 29:4 (2019), 405
M. G. Kostenko, A. V. Lukoyanov, A. A. Valeeva, A. I. Gusev, “Ordering Sequence in Strongly Nonstoichiometric Niobium Carbide with the Formation of Nb6C5-Type Superstructures”, J. Exp. Theor. Phys., 129:5 (2019), 863
Mustafa Burak Cosar, Kerem Cagatay Icli, Macit Ozenbas, “Effect of oxygen flow rate on the low temperature deposition of titanium monoxide thin films via electron beam evaporation”, Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, 37:3 (2019)
Svetlana V. Rempel, Danil A. Eselevich, Evgeny Yu. Gerasimov, Albina A. Valeeva, “Impact of titanium monoxide stoichiometry and heat treatment on the properties of TiOy/HAp nanocomposite”, Journal of Alloys and Compounds, 800 (2019), 412
S. I. Sadovnikov, A. I. Gusev, “Atomic Displacements in the α–β Phase Transition in Ag2S and in Ag2S/Ag Heterostructure”, J. Exp. Theor. Phys., 129:6 (2019), 1005
Andrey A. Rempel, Albina A. Valeeva, Alexey S. Kurlov, Gregor Klinser, Wolfgang Sprengel, “Size effect in nonstoichiometric titanium monoxide and vanadium carbide nanocrystals measured by positron lifetime spectroscopy”, Mendeleev Communications, 29:5 (2019), 486
S. V. Rempel, D. A. Eselevich, A. A. Valeeva, A. A. Rempel, “Structure of a HAp/TiOy Nanocomposite Studied by Vibrational Spectroscopy Techniques”, Inorg Mater, 54:9 (2018), 898
A. A. Valeeva, M. G. Kostenko, S. Z. Nazarova, E. Yu. Gerasimov, A. A. Rempel, “A New Ti9O10 Nanophase Prepared by Heat-Treating Nonstoichiometric Milled TiO y Nanopowder”, Inorg Mater, 54:6 (2018), 568
M. G. Kostenko, A. A. Rempel, “Short-range order and nonstoichiometry in titanium monoxide TiO$_y$ from DFT calculations”, Phys. Solid State, 59:4 (2017), 644–651
Svetlana V. Rempel, Albina A. Valeeva, Ekaterina A. Bogdanova, Hartmut Schroettner, Nail A. Sabirzyanov, Andrey A. Rempel, “Vacuum-made nanocomposite of low-temperature hydroxyapatite and hard nonstoichiometric titanium monoxide with enhanced mechanical properties”, Mendeleev Communications, 26:6 (2016), 543

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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