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This article is cited in 5 scientific papers (total in 5 papers)
Thermochemical and energy characteristics of 1,4-diethylbenzene
D. B. Lempert, I. N. Zyuzin, A. V. Nabatova, A. I. Kazakov, L. S. Yanovskii Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 142432, Russia
Abstract:
The standard enthalpy of formation of 1,4-diethynyl)benzene was determined experimentally to be 500.6 $\pm$ 6.7 kJ/mol. Calculations showed that 1,4-di(ethynyl)benzene has a relatively high adiabatic combustion temperature (about 1970 K at a pressure of 5 atm) and very high heat of combustion in oxygen (42 MJ/kg); therefore, 1,4-di(ethynyl)benzene can be used as the basis to develop an effective dispersant of solid fuel providing an adiabatic combustion temperature of up to 2500 K at a heat of combustion far exceeding the values that provide the HMX and other azides of N-heterocycles previously proposed for this purpose.
Keywords:
1,4-di(ethynyl)benzene, enthalpy of combustion, enthalpy of formation, solid fuel, ramjet engine, burning temperature.
Received: 11.07.2018 Revised: 05.10.2018 Accepted: 24.10.2018
Citation:
D. B. Lempert, I. N. Zyuzin, A. V. Nabatova, A. I. Kazakov, L. S. Yanovskii, “Thermochemical and energy characteristics of 1,4-diethylbenzene”, Fizika Goreniya i Vzryva, 55:6 (2019), 14–18; Combustion, Explosion and Shock Waves, 55:6 (2019), 644–647
Linking options:
https://www.mathnet.ru/eng/fgv627 https://www.mathnet.ru/eng/fgv/v55/i6/p14
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