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Fizika Goreniya i Vzryva, 2019, Volume 55, Issue 5, Pages 3–16
DOI: https://doi.org/10.15372/FGV20190501 (Mi fgv611) 		 
This article is cited in 5 scientific papers (total in 5 papers)

Kinetic analysis of the oxidative conversion of methane in slow combustion. I. Key stages of the chemical mechanism

A. A. Mantashyan, È. M. Makaryan, A. V. Charchyan

Nalbandyan Institute of Chemical Physics, National Academy of Sciences of the Republic of Armenia, Yerevan, 0014, Armenia
Full-text PDF (253 kB) Citations (5)
DOI: https://doi.org/10.15372/FGV20190501
Abstract: This paper presents a kinetic analysis of a chemical model for the oxidative conversion of methane which includes all possible elementary reactions that can occur in this complex radical chain process. It is found that the model fully reflects the kinetic features of degenerate-branched chain reactions. The key stages of the process responsible for the formation of the main reaction products and the development of the process as a whole are identified. The nonlinear reactions of free peroxide radicals play a decisive role in these stages. The results of the kinetic analysis of the model confirm the previously obtained direct experimental data on free radicals and their kinetic behavior during methane oxidation.
Keywords: chain reactions, methane, formaldehyde, methanol, radicals.
Received: 25.05.2018
Revised: 18.07.2018
English version:
Combustion, Explosion and Shock Waves, 2019, Volume 55, Issue 5, Pages 513–525
DOI: https://doi.org/10.1134/S0010508219050010
Bibliographic databases:
Document Type: Article
UDC: 541.124.7
Language: Russian
Citation: A. A. Mantashyan, È. M. Makaryan, A. V. Charchyan, “Kinetic analysis of the oxidative conversion of methane in slow combustion. I. Key stages of the chemical mechanism”, Fizika Goreniya i Vzryva, 55:5 (2019), 3–16; Combustion, Explosion and Shock Waves, 55:5 (2019), 513–525
Citation in format AMSBIB
\Bibitem{ManMakCha19}
\by A.~A.~Mantashyan, \`E.~M.~Makaryan, A.~V.~Charchyan
\paper Kinetic analysis of the oxidative conversion of methane in slow combustion. I. Key stages of the chemical mechanism
\jour Fizika Goreniya i Vzryva
\yr 2019
\vol 55
\issue 5
\pages 3--16
\mathnet{http://mi.mathnet.ru/fgv611}
\crossref{https://doi.org/10.15372/FGV20190501}
\elib{https://elibrary.ru/item.asp?id=41000576}
\transl
\jour Combustion, Explosion and Shock Waves
\yr 2019
\vol 55
\issue 5
\pages 513--525
\crossref{https://doi.org/10.1134/S0010508219050010}
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  • https://www.mathnet.ru/eng/fgv/v55/i5/p3
    • This publication is cited in the following 5 articles:
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
    		Fizika Goreniya i Vzryva Fizika Goreniya i Vzryva
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