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This article is cited in 15 scientific papers (total in 15 papers)
Study of ignition of high-energy materials with boron and diborides of aluminum and titanium
A. G. Korotkikhab, V. A. Arkhipovbc, K. V. Slyusarskiya, I. V. Sorokina a Tomsk Polytechnic University, Tomsk, 634050, Russia
b Tomsk State University, Tomsk, 634050, Russia
c Institute for Problems of Chemical and Energetic Technologies, Siberian Branch, Russian Academy of Sciences, Biisk, 659322, Russia
Abstract:
This paper describes the ignition of high-energy materials (HEMs) on the basis of perchlorate and ammonium nitrate and an active fuel-binder, containing Al powders (base composition), B, AlB$_2$, AlB$_{12}$, and TiB$_2$, upon initiation of the process by a CO$_2$ laser in the heat flux density range 90–200 W/cm$^2$. The delay time of ignition and surface temperature of the reaction layer during the heating-up and ignition of HEMs in air. It is obtained that the complete replacement of the micron-sized aluminum powder by amorphous boron as part of HEMs significantly reduces the delay time of the sample (by 2.2–2.8 times) with the same density of the heat flux, and this occurs due to the high chemical activity and difference between mechanisms of oxidation of boron particles. The use of aluminum diboride in HEMs reduces the ignition delay time by 1.7–2.2 times in comparison with the basic composition. The ignition delay time of a HEM sample with titanium diboride decreases slightly (by 10–25%) relative to the ignition delay of the basic composition.
Keywords:
high-energy material, boron, aluminum diboride, titanium diboride, ignition, activation energy.
Received: 01.09.2017 Revised: 19.10.2017
Citation:
A. G. Korotkikh, V. A. Arkhipov, K. V. Slyusarskiy, I. V. Sorokin, “Study of ignition of high-energy materials with boron and diborides of aluminum and titanium”, Fizika Goreniya i Vzryva, 54:3 (2018), 109–115; Combustion, Explosion and Shock Waves, 54:3 (2018), 350–356
Linking options:
https://www.mathnet.ru/eng/fgv513 https://www.mathnet.ru/eng/fgv/v54/i3/p109
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