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Fizika Goreniya i Vzryva, 2018, Volume 54, Issue 2, Pages 3–14
DOI: https://doi.org/10.15372/FGV20180201
(Mi fgv485)
 

This article is cited in 15 scientific papers (total in 15 papers)

Comparative analysis of the chemical structure of ethyl butanoate and methyl pentanoate flames

A. M. Dmitrievab, K. N. Osipovaab, D. A. Knyaz'kovac, I. E. Gerasimova, A. G. Shmakovab, O. P. Korobeinicheva

a Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Science, Novosibirsk, 630090, Russia
b Novosibirsk State University, Novosibirsk, 630090, Russia
c Far Eastern Federal University, Vladivostok, 690091, Russia
Abstract: The structure of premixed ethyl butanoate/O$_2$/Ar flames stabilized on a flat burner at atmospheric pressure was studied by molecular beam mass spectrometry. Mole fraction profiles of the reactants, stable products, and basic intermediates and temperature profiles were obtained in flames of a stoichiometric $\phi$ = 1) and rich $\phi$ = 1.5) combustible mixtures. Experimental data and their analysis are presented in comparison with experimental and numerical data obtained earlier in methyl pentanoate flames. A simulation of the structure of ethyl butanoate flames was modeled using a detailed literature chemical-kinetic mechanism for the oxidation of esters fatty acids. The experimental profiles are compared with the calculated ones, and the transformation pathways of ethyl butanoate were analyzed. Based on a comparative analysis of experimental and calculated data, the main shortcomings of the model presented in the literature are identified and possible ways to improve the model are suggested. Features of decomposition of ethyl butanoate and methyl pentanoate are discussed based on an analysis of their transformation pathways; similarities and characteristic differences between their oxidation processes due to the different structure of the molecules of the original fuels are outlined.
Keywords: flame structure, molecular beam mass spectrometry, biofuel, combustion mechanism.
Funding agency Grant number
Russian Foundation for Basic Research 15-08-05553
Received: 25.04.2017
Revised: 10.07.2017
English version:
Combustion, Explosion and Shock Waves, 2018, Volume 54, Issue 2, Pages 125–135
DOI: https://doi.org/10.1134/S0010508218020016
Bibliographic databases:
Document Type: Article
UDC: 536.46
Language: Russian
Citation: A. M. Dmitriev, K. N. Osipova, D. A. Knyaz'kov, I. E. Gerasimov, A. G. Shmakov, O. P. Korobeinichev, “Comparative analysis of the chemical structure of ethyl butanoate and methyl pentanoate flames”, Fizika Goreniya i Vzryva, 54:2 (2018), 3–14; Combustion, Explosion and Shock Waves, 54:2 (2018), 125–135
Citation in format AMSBIB
\Bibitem{DmiOsiKny18}
\by A.~M.~Dmitriev, K.~N.~Osipova, D.~A.~Knyaz'kov, I.~E.~Gerasimov, A.~G.~Shmakov, O.~P.~Korobeinichev
\paper Comparative analysis of the chemical structure of ethyl butanoate and methyl pentanoate flames
\jour Fizika Goreniya i Vzryva
\yr 2018
\vol 54
\issue 2
\pages 3--14
\mathnet{http://mi.mathnet.ru/fgv485}
\crossref{https://doi.org/10.15372/FGV20180201}
\elib{https://elibrary.ru/item.asp?id=32819286}
\transl
\jour Combustion, Explosion and Shock Waves
\yr 2018
\vol 54
\issue 2
\pages 125--135
\crossref{https://doi.org/10.1134/S0010508218020016}
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  • This publication is cited in the following 15 articles:
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