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Fizika Goreniya i Vzryva, 2016, Volume 52, Issue 4, Pages 3–14
DOI: https://doi.org/10.15372/FGV20160401 (Mi fgv334) 		 
This article is cited in 9 scientific papers (total in 9 papers)

Promoting effect of halogenand phosphorus-containing flame retardants on the autoignition of a methane-oxygen mixture

A. V. Drakona, A. V. Eremina, O. P. Korobeinichevb, V. M. Shvartsbergb, A. G. Shmakovbc

a Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow, 125412, Russia
b Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia
c Novosibirsk State University, Novosibirsk, 630090, Russia
Full-text PDF (250 kB) Citations (9)
DOI: https://doi.org/10.15372/FGV20160401
Abstract: This paper presents a numerical and experimental study of the effect of flame-retardant additives on the autoignition of methane behind shock waves. It is shown that at a temperature of 11300–1900 K, the compounds CCl$_4$, CF$_3$H, (СН$_3$О)$_3$РО not only do not suppress ignition but significantly reduce the induction time of methane-oxygen mixtures. A kinetic mechanism is proposed which relates the promoting effect to the reactivity of the pyrolysis products of the additives.
Keywords: methane, ignition, flame inhibition, additives, halogen, phosphoru.
Received: 28.07.2015
English version:
Combustion, Explosion and Shock Waves, 2016, Volume 52, Issue 4, Pages 375–385
DOI: https://doi.org/10.1134/S0010508216040018
Bibliographic databases:
Document Type: Article
UDC: 544.45
Language: Russian
Citation: A. V. Drakon, A. V. Eremin, O. P. Korobeinichev, V. M. Shvartsberg, A. G. Shmakov, “Promoting effect of halogenand phosphorus-containing flame retardants on the autoignition of a methane-oxygen mixture”, Fizika Goreniya i Vzryva, 52:4 (2016), 3–14; Combustion, Explosion and Shock Waves, 52:4 (2016), 375–385
Citation in format AMSBIB
\Bibitem{DraEreKor16}
\by A.~V.~Drakon, A.~V.~Eremin, O.~P.~Korobeinichev, V.~M.~Shvartsberg, A.~G.~Shmakov
\paper Promoting effect of halogenand phosphorus-containing flame retardants on the autoignition of a methane-oxygen mixture
\jour Fizika Goreniya i Vzryva
\yr 2016
\vol 52
\issue 4
\pages 3--14
\mathnet{http://mi.mathnet.ru/fgv334}
\crossref{https://doi.org/10.15372/FGV20160401}
\elib{https://elibrary.ru/item.asp?id=26416898}
\transl
\jour Combustion, Explosion and Shock Waves
\yr 2016
\vol 52
\issue 4
\pages 375--385
\crossref{https://doi.org/10.1134/S0010508216040018}
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    • This publication is cited in the following 9 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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