Structure of ultrahigh molecular weight polyethylene-air counterflow flame

The combustion of ultrahigh molecular weight polyethylene (UHMWPE) in airflow perpendicular to the polyethylene surface (counterflow flame) was studied in detail. The burning rate of pressed samples of UHMWPE was measured. The structure of the UHMWPE-air counterflow flame was first determined by mass spectrometric sampling taking into account heavy products. The composition of the main pyrolysis products was investigated by mass spectrometry, and the composition of heavy hydrocarbons (С$_7$-С$_{25}$) in products sampled from the flame at a distance of 0.8 mm from the UHMWPE surface was analyzed by gas-liquid chromatography mass-spectrometry. The temperature and concentration profiles of eight species (N$_2$, O$_2$, СО$_2$, СО, Н$_2$О, С$_3$Н$_6$, С$_4$Н$_6$, С$_6$Н$_6$) and a hypothetical species with an average molecular weight of 258.7 g/mol, which simulates more than 50 С$_7$-С$_{25}$ hydrocarbons were measured. The structure of the diffusion flame of the model mixture of decomposition products of UHMWPE in air counterflow was simulated using the OPPDIF code from the CHEMKIN II software package. The simulation results are in good agreement with experimental data on combustion of UHMWPE.