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Fizika Goreniya i Vzryva, 1997, Volume 33, Issue 3, Pages 32–48 (Mi fgv2560)  

This article is cited in 6 scientific papers (total in 6 papers)

Destruction chemistry of organophosphorus compounds in hydrogen-oxygen flames

O. P. Korobeinichev, V. M. Shvartsberg, S. B. Il'in

Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Science, Novosibirsk 630090
Citations (6)
Abstract: A review of the results of experimental studies of the destruction chemistry of organophosphorus compounds modeling sarin in hydrogen-oxygen rarefied flames is presented. These studies were performed at the Institute of Chemical Kinetics and Combustion of the Siberian Division of the Russian Academy of Sciences by soft ionization probe molecular beam mass spectrometry. A method is described that allows one to identify almost all starting, intermediate (including atoms and free radicals), and final organophosphorus compounds and to measure concentration profiles in flames. The destruction products of organophosphorus compounds – dimethyl methylphosphonate and trimethylphosphate – are identified in various zones of an H$_2$/O$_2$/Ar flame. Mass peak intensities proportional to the concentrations of the indicated products are measured. The inhibition and promotion phenomena of the flames are discovered and studied. A chemical mechanism for the destruction of organophosphorus compounds in the flames is proposed. The results obtained are important for understanding the processes involved in the incineration of chemical warfare agents and munitions and other toxic and hazardous substances, for optimization of this technology, and also for understanding the inhibition and promotion mechanisms of flames.
Received: 28.01.1997
English version:
Combustion, Explosion and Shock Waves, 1997, Volume 33, Issue 3, Pages 270–283
DOI: https://doi.org/10.1007/BF02671866
Bibliographic databases:
Document Type: Article
UDC: 542.41.623.459
Language: Russian
Citation: O. P. Korobeinichev, V. M. Shvartsberg, S. B. Il'in, “Destruction chemistry of organophosphorus compounds in hydrogen-oxygen flames”, Fizika Goreniya i Vzryva, 33:3 (1997), 32–48; Combustion, Explosion and Shock Waves, 33:3 (1997), 270–283
Citation in format AMSBIB
\Bibitem{KorShvIli97}
\by O.~P.~Korobeinichev, V.~M.~Shvartsberg, S.~B.~Il'in
\paper Destruction chemistry of organophosphorus compounds in hydrogen-oxygen flames
\jour Fizika Goreniya i Vzryva
\yr 1997
\vol 33
\issue 3
\pages 32--48
\mathnet{http://mi.mathnet.ru/fgv2560}
\elib{https://elibrary.ru/item.asp?id=15345809}
\transl
\jour Combustion, Explosion and Shock Waves
\yr 1997
\vol 33
\issue 3
\pages 270--283
\crossref{https://doi.org/10.1007/BF02671866}
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  • This publication is cited in the following 6 articles:
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
    Fizika Goreniya i Vzryva Fizika Goreniya i Vzryva
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