Abstract:
Burning rates of hydrazine borane at a pressure of 20–100 atm have been measured. Spectroscopic and electron microscopic studies have demonstrated that the condensed combustion product is a fine powder of boron nitride. Thermal decomposition of hydrazine borane has been studied. The obtained kinetic data and physicochemical properties of the materials and the foam combustion model have been used to calculate the pressure dependence of the burning rate of hydrazine borane, which agrees with the experimental one. The obtained degree of conversion of the material to boron nitride indicates the possibility of using hydrazine borane and similar compounds in high-performance systems.
Citation:
G. B. Manelis, V. V. Zakharov, G. N. Nechiporenko, V. A. Strunin, A. V. Raevskii, V. V. Yakovlev, “Combustion and thermal decomposition of hydrazine borane”, Fizika Goreniya i Vzryva, 51:4 (2015), 72–76; Combustion, Explosion and Shock Waves, 51:4 (2015), 462–466
\Bibitem{ManZakNec15}
\by G.~B.~Manelis, V.~V.~Zakharov, G.~N.~Nechiporenko, V.~A.~Strunin, A.~V.~Raevskii, V.~V.~Yakovlev
\paper Combustion and thermal decomposition of hydrazine borane
\jour Fizika Goreniya i Vzryva
\yr 2015
\vol 51
\issue 4
\pages 72--76
\mathnet{http://mi.mathnet.ru/fgv246}
\crossref{https://doi.org/10.15372/FGV20150409}
\elib{https://elibrary.ru/item.asp?id=24086894}
\transl
\jour Combustion, Explosion and Shock Waves
\yr 2015
\vol 51
\issue 4
\pages 462--466
\crossref{https://doi.org/10.1134/S0010508215040097}
Linking options:
https://www.mathnet.ru/eng/fgv246
https://www.mathnet.ru/eng/fgv/v51/i4/p72
This publication is cited in the following 3 articles:
Libo Sheng, Guangyu Qi, Kaixiang Jin, Ankang Chen, Xiaoli Huang, Guangtao Liu, Mi Zhou, Hongbo Wang, Yan Li, Kai Wang, Yongming Sui, Bo Zou, “Pressure Strategy To Improve H Atomic Utilization via Optimized Decomposition Pathway in Solid Hydrazine Borane”, J. Phys. Chem. Lett., 2024, 9939
Carlos A. Castilla-Martinez, Lucas Roussignol, Umit B. Demirci, “Magnesium hydrazinidoborane: Synthesis, characterization and features for solid-state hydrogen storage”, International Journal of Hydrogen Energy, 46:66 (2021), 33164
Carlos A. Castilla-Martinez, Romain Moury, Umit B. Demirci, “Amidoboranes and hydrazinidoboranes: State of the art, potential for hydrogen storage, and other prospects”, International Journal of Hydrogen Energy, 45:55 (2020), 30731
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