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This article is cited in 5 scientific papers (total in 5 papers)
Soot formation in isothermal pyrolysis of carbon tetrachloride and its mixture with methane
S. V. Shurupov, P. A. Tesner Institute of Natural Gases and Gas Technologies, 142717, Moscow Region, Razvilka
Abstract:
The formation of soot during pyrolysis of tetrachloride carbon in the temperature interval 1423–1623 K and its mixtures with methane at 1573 K is studied under conditions close to the isothermal ones. The induction periods of soot formation from ССl$_4$ are measured. The equations to calculate the induction period of soot formation, the concentration of soot particles, and its specific surface as a function of the temperature and concentration of ССl$_4$ are derived. The inhibition of soot formation is observed in the isothermal pyrolysis of a ССl$_4$ – СН$_4$ mixture. It is shown that the particle nuclei are formed only from ССl$_4$, and the CH$_4$ molecules are spent only for the heterogeneous growth of the formed particles.
Received: 10.12.1997 Accepted: 07.12.1998
Citation:
S. V. Shurupov, P. A. Tesner, “Soot formation in isothermal pyrolysis of carbon tetrachloride and its mixture with methane”, Fizika Goreniya i Vzryva, 35:4 (1999), 41–47; Combustion, Explosion and Shock Waves, 35:4 (1999), 386–392
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https://www.mathnet.ru/eng/fgv2353 https://www.mathnet.ru/eng/fgv/v35/i4/p41
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