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Fizika Goreniya i Vzryva, 2023, Volume 59, Issue 6, Pages 42–51
DOI: https://doi.org/10.15372/FGV2022.9234 (Mi fgv2301) 		 
Calculation of thermochemical and detonation parameters of azidoacetylene derivatives of $s$-triazine

A. O. Petrova, S. V. Karpova, A. V. Darovskikha, A. S. Dzhalmukhanovaa, T. A. Pugachevaa, V. A. Garanina, D. B. Lemperta, L. S. Yanovskiiabc, G. V. Malkova, E. R. Badamshinaa

a Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, 142342 Russia
b National Research University MPEI, Moscow, Russia
c Moscow Aviation Institute (National Research University), Moscow, Russia
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DOI: https://doi.org/10.15372/FGV2022.9234
Abstract: The properties of azidoacetylene derivatives of $s$-triazine containing various combinations of propynyloxy, propynylamino, N-methyl-propynylamino and azido groups have been studied, and their enthalpy of formation in the condensed phase, density, and impact and friction sensitivity have been determined. Based on these data, the energy parameters of the detonation, combustion, and adiabatic transformation of both individual compounds and their compositions with SKI-3 binding isoprene rubber have been calculated. The results of the integrated experimental and theoretical studies lead to the conclusion about the high calorific value of the investigated individual compounds and compositions based on them.
Keywords: azidoacetylene derivatives of $s$-triazine, energetic condensed materials, detonation, combustion, adiabatic transformation.
Funding agency Grant number
Ministry of Science and Higher Education of the Russian Federation 075-15-2020-803
Received: 11.10.2022
Revised: 23.12.2022
Accepted: 01.02.2023
English version:
Combustion, Explosion and Shock Waves, 2023, Volume 59, Issue 6, Pages 707–715
DOI: https://doi.org/10.1134/S0010508223060060
Bibliographic databases:
Document Type: Article
UDC: 544.32.2+662, 662.611
Language: Russian
Citation: A. O. Petrov, S. V. Karpov, A. V. Darovskikh, A. S. Dzhalmukhanova, T. A. Pugacheva, V. A. Garanin, D. B. Lempert, L. S. Yanovskii, G. V. Malkov, E. R. Badamshina, “Calculation of thermochemical and detonation parameters of azidoacetylene derivatives of $s$-triazine”, Fizika Goreniya i Vzryva, 59:6 (2023), 42–51; Combustion, Explosion and Shock Waves, 59:6 (2023), 707–715
Citation in format AMSBIB
\Bibitem{PetKarDar23}
\by A.~O.~Petrov, S.~V.~Karpov, A.~V.~Darovskikh, A.~S.~Dzhalmukhanova, T.~A.~Pugacheva, V.~A.~Garanin, D.~B.~Lempert, L.~S.~Yanovskii, G.~V.~Malkov, E.~R.~Badamshina
\paper Calculation of thermochemical and detonation parameters of azidoacetylene derivatives of $s$-triazine
\jour Fizika Goreniya i Vzryva
\yr 2023
\vol 59
\issue 6
\pages 42--51
\mathnet{http://mi.mathnet.ru/fgv2301}
\crossref{https://doi.org/10.15372/FGV2022.9234}
\elib{https://elibrary.ru/item.asp?id=54815401}
\transl
\jour Combustion, Explosion and Shock Waves
\yr 2023
\vol 59
\issue 6
\pages 707--715
\crossref{https://doi.org/10.1134/S0010508223060060}
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