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This article is cited in 23 scientific papers (total in 23 papers)
Enhancement of combustion of a hydrogen-air mixture by excitation of O$_2$ molecules to the $a^1\Delta_g$ state state
V. E. Kozlov, A. M. Starik, N. S. Titova Central Institute of Aviation Motors, State Scientific Center of Russian Federation, 111116, Russia
Abstract:
The possibility of increasing the laminar flame velocity in a hydrogen-air mixture by excitation of O$_2$ molecules into the $a^1\Delta_g$ singlet state. The presence of 10% of O$_2$($a^1\Delta_g$) molecules in oxygen is demonstrated to result in noticeable (up to 50%) enhancement of mixture burning. The temperature of combustion products and also the concentrations of H$_2$O, NO, and other constituents increase. The greatest effect of O$_2$($a^1\Delta_g$) molecules is manifested in combustion of lean mixtures; the least pronounced effect is observed in rich mixtures. These effects are caused by intensification of the chain mechanism in the presence of a super-equilibrium amount of excited O$_2$($a^1\Delta_g$) molecules in a hydrogen-air mixture.
Keywords:
hydrogen-air mixture, singlet oxygen, laminar flame.
Received: 01.06.2007 Accepted: 20.12.2007
Citation:
V. E. Kozlov, A. M. Starik, N. S. Titova, “Enhancement of combustion of a hydrogen-air mixture by excitation of O$_2$ molecules to the $a^1\Delta_g$ state state”, Fizika Goreniya i Vzryva, 44:4 (2008), 3–12; Combustion, Explosion and Shock Waves, 44:4 (2008), 371–379
Linking options:
https://www.mathnet.ru/eng/fgv1407 https://www.mathnet.ru/eng/fgv/v44/i4/p3
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