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This article is cited in 5 scientific papers (total in 5 papers)
Effect of trimethylphosphate additives on the flammability concentration limits of premixed methane-air mixtures
D. A. Knyaz'kov, S. A. Yakimov, O. P. Korobeinichev, A. G. Shmakov Institute of Chemical Kinetics and Combustion, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090
Abstract:
The effect of small additives of trimethylphosphate (TMP) on the lean and rich flammability concentration limits of CH$_4$/air gas mixtures were studied using an opposed-flow burner and numerical modeling based on detailed kinetic mechanisms. TMP was found to narrow the flammability concentration limits of premixed CH$_4$/air mixtures. Modeling using a previously developed model for flame inhibition by phosphorus compounds showed that the model provides a satisfactory fit to experimental results on the effect of TMP additives on the lean concentration limit.
Keywords:
flammability concentration limits, opposed-flow premixed flame, organophosphorus compounds.
Received: 12.01.2007
Citation:
D. A. Knyaz'kov, S. A. Yakimov, O. P. Korobeinichev, A. G. Shmakov, “Effect of trimethylphosphate additives on the flammability concentration limits of premixed methane-air mixtures”, Fizika Goreniya i Vzryva, 44:1 (2008), 12–21; Combustion, Explosion and Shock Waves, 44:1 (2008), 9–17
Linking options:
https://www.mathnet.ru/eng/fgv1363 https://www.mathnet.ru/eng/fgv/v44/i1/p12
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