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Fizika Goreniya i Vzryva, 2011, Volume 47, Issue 1, Pages 3–14 (Mi fgv1061)  
This article is cited in 6 scientific papers (total in 6 papers)

Structure of an atmospheric-pressure H$_2$/O$_2$/N$_2$ flame doped with iron pentacarbonyl

I. E. Gerasimovab, D. A. Knyaz'kova, A. G. Shmakova, A. A. Paletskya, V. M. Shvartsberga, T. A. Bolshovaa, O. P. Korobeinicheva

a Institute of Chemical Kinetics and Combustion, Siberian Division, Russian Academy of Scienses, Novosibirsk, 630090, Russia
b Novosibirsk State University, Novosibirsk, 630090, Russia
Citations (6)
Abstract: This paper presents the measurement and simulation data on the thermal and chemical structure of an atmospheric-pressure premixed H$_2$/O$_2$/N$_2$ flame doped with iron pentacarbonyl Fe(CO)$_5$. Soft ionization molecular beam mass spectrometry was used to measure concentration profiles of the combustion products of iron pentacarbonyl: Fe, FeO$_2$, FeOH, and Fe(OH)$_2$. A comparison of experimental and simulated concentration profiles showed that they are in satisfactory agreement for FeO$_2$ and Fe(OH)$_2$ and differ significantly for Fe and FeOH. Thus, the previously proposed kinetic model for the oxidation of iron pentacarbonyl was tested and it was shown that the mechanism needs further elaboration.
Keywords: flame inhibition, iron pentacarbonyl, flame structure, reaction mechanism, molecular beam mass spectrometry.
Received: 13.01.2010
English version:
Combustion, Explosion and Shock Waves, 2011, Volume 47, Issue 1, Pages 1–11
DOI: https://doi.org/10.1134/S0010508211010011
Bibliographic databases:
Document Type: Article
UDC: 536.46+531.3
Language: Russian
Citation: I. E. Gerasimov, D. A. Knyaz'kov, A. G. Shmakov, A. A. Paletsky, V. M. Shvartsberg, T. A. Bolshova, O. P. Korobeinichev, “Structure of an atmospheric-pressure H$_2$/O$_2$/N$_2$ flame doped with iron pentacarbonyl”, Fizika Goreniya i Vzryva, 47:1 (2011), 3–14; Combustion, Explosion and Shock Waves, 47:1 (2011), 1–11
Citation in format AMSBIB
\Bibitem{GerKnyShm11}
\by I.~E.~Gerasimov, D.~A.~Knyaz'kov, A.~G.~Shmakov, A.~A.~Paletsky, V.~M.~Shvartsberg, T.~A.~Bolshova, O.~P.~Korobeinichev
\paper Structure of an atmospheric-pressure H$_2$/O$_2$/N$_2$ flame doped with iron pentacarbonyl
\jour Fizika Goreniya i Vzryva
\yr 2011
\vol 47
\issue 1
\pages 3--14
\mathnet{http://mi.mathnet.ru/fgv1061}
\elib{https://elibrary.ru/item.asp?id=16232871}
\transl
\jour Combustion, Explosion and Shock Waves
\yr 2011
\vol 47
\issue 1
\pages 1--11
\crossref{https://doi.org/10.1134/S0010508211010011}
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  • https://www.mathnet.ru/eng/fgv/v47/i1/p3
    • This publication is cited in the following 6 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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