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Fizika Goreniya i Vzryva, 2012, Volume 48, Issue 6, Pages 3–20 (Mi fgv1049)  
This article is cited in 4 scientific papers (total in 4 papers)

Effect of ethanol on the chemistry of formation of precursors of polyaromatic hydrocarbons in a fuel-rich ethylene flame at atmospheric pressure

I. E. Gerasimovab, D. A. Knyaz'kova, S. A. Yakimova, T. A. Bolshovaa, A. G. Shmakova, O. P. Korobeinicheva

a Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia
b Novosibirsk State University, Novosibirsk, 630090, Russia
Citations (4)
Abstract: The effect of the addition of ethanol (EtOH) to the initial combustible mixture on the concentration of various compounds, in particular, those preceding the formation of polyaromatic hydrocarbons in a fuel-rich (equivalence ratio of fuel $\phi$ = 1.7) flat premixed ethylene/oxygen/argon flame at atmospheric pressure was studied experimentally and by numerical modeling using a detailed mechanism of chemical reactions. Concentrations of various stable and labile species, including reactants, major combustion products, and intermediates in C$_2$H$_4$/O$_2$/Ar and C$_2$H$_4$/EtOH/O$_2$/Ar flames were measured along the height above the burner using molecular beam mass spectrometry. Experimental mole fraction profiles were compared with those calculated using the previously proposed mechanisms of chemical reactions. This mechanism was analyzed to determine the cause of the ethanol effect on the flame concentration of propargyl, the main precursor of polyaromatic hydrocarbons.
Keywords: ethylene flame, ethanol, molecular beam mass spectrometry, flame structure, formation of soot precursors.
Received: 20.04.2011
Accepted: 23.09.2011
English version:
Combustion, Explosion and Shock Waves, 2012, Volume 48, Issue 6, Pages 661–676
DOI: https://doi.org/10.1134/S0010508212060019
Bibliographic databases:
Document Type: Article
UDC: 536.461, 536.462
Language: Russian
Citation: I. E. Gerasimov, D. A. Knyaz'kov, S. A. Yakimov, T. A. Bolshova, A. G. Shmakov, O. P. Korobeinichev, “Effect of ethanol on the chemistry of formation of precursors of polyaromatic hydrocarbons in a fuel-rich ethylene flame at atmospheric pressure”, Fizika Goreniya i Vzryva, 48:6 (2012), 3–20; Combustion, Explosion and Shock Waves, 48:6 (2012), 661–676
Citation in format AMSBIB
\Bibitem{GerKnyYak12}
\by I.~E.~Gerasimov, D.~A.~Knyaz'kov, S.~A.~Yakimov, T.~A.~Bolshova, A.~G.~Shmakov, O.~P.~Korobeinichev
\paper Effect of ethanol on the chemistry of formation of precursors of polyaromatic hydrocarbons in a fuel-rich ethylene flame at atmospheric pressure
\jour Fizika Goreniya i Vzryva
\yr 2012
\vol 48
\issue 6
\pages 3--20
\mathnet{http://mi.mathnet.ru/fgv1049}
\elib{https://elibrary.ru/item.asp?id=18807198}
\transl
\jour Combustion, Explosion and Shock Waves
\yr 2012
\vol 48
\issue 6
\pages 661--676
\crossref{https://doi.org/10.1134/S0010508212060019}
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  • https://www.mathnet.ru/eng/fgv/v48/i6/p3
    • This publication is cited in the following 4 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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