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Fizika Goreniya i Vzryva, 2012, Volume 48, Issue 5, Pages 97–108 (Mi fgv1040)  
This article is cited in 5 scientific papers (total in 5 papers)

Reducing the flammability of ultra-high-molecular-weight polyethylene by triphenyl phosphate additives

M. B. Gonchikzhapovab, A. A. Paletskya, L. V. Kuibidaa, I. K. Shundrinac, O. P. Korobeinicheva

a Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Science, 630090, Russia
b Novosibirsk State University, Novosibirsk, 630090, Russia
c Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia
Citations (5)
Abstract: The thermal degradation and combustion of ultra-high-molecular-weight polyethylene (UHMWPE) doped with triphenyl phosphate (TPP) at atmospheric pressure was studied by molecular beam mass spectrometry, dynamic mass spectrometric thermal analysis, microthermocouples, thermogravimetry, gas chromatography/mass spectrometry. The kinetics of thermal degradation of pure UHMWPE and that mixed with TPP at high ($\approx$150 K/s) and low (0.17 K/s) heating rates was investigated. The effective values of the rate constant and activation energy of the thermal degradation reaction were determined. Burning velocity and temperature profiles in UHMWPE and UHMWPE + TPP flames were measured. The composition of the combustion products in a flame zone adjacent to the burning surface of the sample was determined. TPP vapor in the flame was detected. The addition of TPP to UHMWPE was found to reduce the flammability of the polymer. It is shown that TPP acts as a fire retardant in both the condensed and gas phases.
Keywords: UHMWPE, triphenyl phosphate, flame retardant, degradation kinetics, burning velocity, composition of combustion products.
Received: 14.12.2011
Accepted: 06.04.2012
English version:
Combustion, Explosion and Shock Waves, 2012, Volume 48, Issue 5, Pages 579–589
DOI: https://doi.org/10.1134/S0010508212050097
Bibliographic databases:
Document Type: Article
UDC: 541.124
Language: Russian
Citation: M. B. Gonchikzhapov, A. A. Paletsky, L. V. Kuibida, I. K. Shundrina, O. P. Korobeinichev, “Reducing the flammability of ultra-high-molecular-weight polyethylene by triphenyl phosphate additives”, Fizika Goreniya i Vzryva, 48:5 (2012), 97–108; Combustion, Explosion and Shock Waves, 48:5 (2012), 579–589
Citation in format AMSBIB
\Bibitem{GonPalKui12}
\by M.~B.~Gonchikzhapov, A.~A.~Paletsky, L.~V.~Kuibida, I.~K.~Shundrina, O.~P.~Korobeinichev
\paper Reducing the flammability of ultra-high-molecular-weight polyethylene by triphenyl phosphate additives
\jour Fizika Goreniya i Vzryva
\yr 2012
\vol 48
\issue 5
\pages 97--108
\mathnet{http://mi.mathnet.ru/fgv1040}
\elib{https://elibrary.ru/item.asp?id=17974583}
\transl
\jour Combustion, Explosion and Shock Waves
\yr 2012
\vol 48
\issue 5
\pages 579--589
\crossref{https://doi.org/10.1134/S0010508212050097}
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    • This publication is cited in the following 5 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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